NDLI: Morphology-Dependent Electrochemical Performance of Zinc Hexacyanoferrate Cathode for Zinc-Ion Battery

Content Provider	PubMed Central
Author	Zhang, Leyuan Chen, Liang Zhou, Xufeng Liu, Zhaoping
Copyright Year	2015
Abstract	Zinc hexacyanoferrate (ZnHCF) which is a dimorphic (cubic or rhombohedral) Prussian blue analogue and can be intercalated by both monovalent and divalent ions,is a promising cathode material for rechargeable aqueous metal-ion batteries.In this paper, a simple co-precipitation method is developed to tune the particle morphology of ZnHCF by adjusting the dropping speed at room temperature. Three polyhedral ZnHCF particles, with cubooctahedral, truncated octahedral or octahedral shapes, are obtained at room temperature. Structural transformation from cubic phase of as-prepared ZnHCF to rhombohedral phase is observed by further dehydration of the sample at 70 °C, whereas the dehydrated ZnHCF crystals still hold the identical polyhedral shape as that of the cubic phase particles. Then the influence of shape and facets on electrochemical performance is studied for polyhedral ZnHCF with rhombohedral structure (RZnHCF). RZnHCF sample with cubooctahedral shape possesses the best rate capability and cyclic stability comparing with RZnHCF particles having truncated octahedral or octahedral shapes. Furthermore, the structure of cuboctahedron RZnHCF particles during electrochemical cycling has been monitored with ex situ X-ray diffraction to demonstrate the reversible zinc-ion intercalation mechanism.
Related Links	http://dx.doi.org/10.1038/srep18263
Starting Page	18263
File Format	PDF
ISSN	20452322
e-ISSN	20452322
Journal	Scientific Reports
Volume Number	5
Language	English
Publisher	Nature Publishing Group
Publisher Date	2015-12-01
Access Restriction	Open
Rights Holder	Nature Publishing Group
Subject Keyword	Science and technology Research in Higher Education
Content Type	Text
Resource Type	Article
Subject	Multidisciplinary

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Morphology-Dependent Electrochemical Performance of Zinc Hexacyanoferrate Cathode for Zinc-Ion Battery

Sustainable Sulfur-rich Copolymer/Graphene Composite as Lithium-Sulfur Battery Cathode with Excellent Electrochemical Performance

Synthesis and electrochemical performance of Sn-doped LiNi0.5Mn1.5O4 cathode material for high-voltage lithium-ion batteries

Electrochemical Performance and Resistance Analysis of Li3V2(PO4)3/C Composite Cathode for Li Ion Battery

Employing Synergetic Effect of Doping and Thin Film Coating to Boost the Performance of Lithium-Ion Battery Cathode Particles

Challenges and Perspectives for Doping Strategy for Manganese-Based Zinc-ion Battery Cathode

Morphology Controllable Synthesis of NiO/NiFe2O4 Hetero-Structures for Ultrafast Lithium-Ion Battery

Enhancement of Electrochemical Performance of LiMn2O4 Spinel Cathode Material by Synergetic Substitution with Ni and S

A new cathode material for super-valent battery based on aluminium ion intercalation and deintercalation

Morphology-Dependent Electrochemical Performance of Zinc Hexacyanoferrate Cathode for Zinc-Ion Battery

Similar Documents

Morphology-Dependent Electrochemical Performance of Zinc Hexacyanoferrate Cathode for Zinc-Ion Battery

Sustainable Sulfur-rich Copolymer/Graphene Composite as Lithium-Sulfur Battery Cathode with Excellent Electrochemical Performance

Synthesis and electrochemical performance of Sn-doped LiNi0.5Mn1.5O4 cathode material for high-voltage lithium-ion batteries

Electrochemical Performance and Resistance Analysis of Li3V2(PO4)3/C Composite Cathode for Li Ion Battery

Employing Synergetic Effect of Doping and Thin Film Coating to Boost the Performance of Lithium-Ion Battery Cathode Particles

Challenges and Perspectives for Doping Strategy for Manganese-Based Zinc-ion Battery Cathode

Morphology Controllable Synthesis of NiO/NiFe2O4 Hetero-Structures for Ultrafast Lithium-Ion Battery

Enhancement of Electrochemical Performance of LiMn2O4 Spinel Cathode Material by Synergetic Substitution with Ni and S

A new cathode material for super-valent battery based on aluminium ion intercalation and deintercalation

Morphology-Dependent Electrochemical Performance of Zinc Hexacyanoferrate Cathode for Zinc-Ion Battery