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Content Provider | IEEE Xplore Digital Library |
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Author | Provenzano, V. Tiebang Zhang Shapiro, A. Chen, Y.G. Shull, R.D. |
Copyright Year | 1965 |
Abstract | In this study the magnetic properties and the structure of Gd5Ge1.8Si1.8Sn0.4 alloy were investigated by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and magnetometry. The concentration of the Sn-doping in this study is four times that used in previous studies examining the magnetocaloric properties of the Gd5Ge2Si2 compound doped with different metal additives. In the earlier studies it was shown the addition of about one atom percent of either Fe, Cu, Co, Ga, Mn, or Al nearly eliminated the large hysteresis losses present in the undoped Gd5Ge2Si2 compound between 270 K and 300 K. Also, these metal additives affected the characteristics DeltaSm versus T peak, resulting in a significant increase in the refrigeration capacity of the material, if the hysteresis losses are taken into account. By contrast, the same amount of either Sn or Bi had much smaller effects on both the hysteresis losses and the characteristics of the DeltaSm versus T peak. In this study, a larger amount of Sn doping had a limited effect on the hysteresis losses and characteristics of the DeltaSm versus T peak of Gd5Ge2Si2 . But, most importantly, it resulted in a different microstructure compared to the compound with smaller Sn addition. The implications of the larger Sn doping on both the magnetocaloric properties and structure of the Gd5Ge2Si2 compound are discussed. |
Sponsorship | IEEE Magnetics Society |
Starting Page | 3048 |
Ending Page | 3051 |
Page Count | 4 |
File Size | 641424 |
File Format | |
ISSN | 00189464 |
Volume Number | 44 |
Issue Number | 11 |
Language | English |
Publisher | Institute of Electrical and Electronics Engineers, Inc. (IEEE) |
Publisher Date | 2008-11-01 |
Publisher Place | U.S.A. |
Access Restriction | One Nation One Subscription (ONOS) |
Rights Holder | Institute of Electrical and Electronics Engineers, Inc. (IEEE) |
Subject Keyword | Magnetic properties Tin Magnetic hysteresis Scanning electron microscopy Additives Doping Germanium alloys Silicon alloys Powders X-ray diffraction Sn-doped GdGeSi compound Field-induced transition hysteresis losses magnetocaloric properties |
Content Type | Text |
Resource Type | Article |
Subject | Electronic, Optical and Magnetic Materials Electrical and Electronic Engineering |
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