NDLI: Pollutant emissions and environmental assessment of ethyl 3-ethoxybutyrate, a potential renewable fuel.

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Pollutant emissions and environmental assessment of ethyl 3-ethoxybutyrate, a potential renewable fuel.

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Pollutant emissions and environmental assessment of ethyl 3-ethoxybutyrate, a potential renewable fuel.

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Ritchie, Stephen M. C. Clarke, Edwina M. Bunce, Michael P. Findlay, Robert H. McMurry, Zackery A. Smoot, James C. Edmonds, Jennifer W. Eyers, Laurent Storey, John M. E.
Description	Country affiliation: United States Author Affiliation: Storey JM ( Fuels, Engines, and Emissions Research Center, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA.); Bunce MP ( Fuels, Engines, and Emissions Research Center, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA.); Clarke EM ( MAHLE Powertrain, LLC, Farmington Hills, MI, 48337, USA.); Edmonds JW ( Department of Biological Sciences, University of Alabama, Tuscaloosa, AL, 35487, USA.); Findlay RH ( Feinberg School of Medicine, Northwestern University, Chicago, IL, 60611, USA.); Ritchie SM ( Department of Biological Sciences, University of Alabama, Tuscaloosa, AL, 35487, USA.); Eyers L ( Physical and Life Sciences, Nevada State College, Henderson, NV, 89002, USA.); McMurry ZA ( Department of Biological Sciences, University of Alabama, Tuscaloosa, AL, 35487, USA.); Smoot JC ( Department of Chemical and Biological Engineering, University of Alabama, Tuscaloosa, AL, 35487, USA.)
Abstract	Renewable and bio-based transportation fuel sources can lower the life-cycle greenhouse gas emissions from vehicles. We present an initial assessment of ethyl 3-ethoxybutyrate (EEB) as a biofuel in terms of its performance as a fuel oxygenate and its persistence in the environment. EEB can be produced from ethanol and poly-3-hydroxybutyrate, a bacterial storage polymer that can be produced from non-food biomass and other organic feedstocks. Physicochemical properties of EEB and fuel-relevant properties of EEB-gasoline blends were measured, emissions of criteria pollutants from EEB as a gasoline additive in a production vehicle were evaluated, and fate and persistence of EEB in the environment were estimated. EEB solubility in water was 25.8 g/L, its Kow was 1.8, and its Henry's Law constant was 1.04 × 10(-5) atm-m(3)/mole. The anti-knock index values for 5 and 20 % v/v EEB-gasoline blends were 91.6 and 91.9, respectively. Reductions in fuel economy were consistent with the level of oxygenation, and criteria emissions were met by the vehicle operated over the urban dynamometer driving cycle (FTP 75). Predicted environmental persistence ranged from 15 to 30 days which indicates that EEB is not likely to be a persistent organic pollutant. In combination, these results suggest a high potential for the use of EEB as a renewable fuel source.
ISSN	09441344
Issue Number	18
Journal	Environmental Science and Pollution Research
Volume Number	23
e-ISSN	16147499
Language	English
Publisher	Springer
Publisher Date	2016-09-01
Publisher Place	Germany
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Discipline Environmental Science Discipline Environmental Chemistry
Content Type	Text
Resource Type	Article
Subject	Environmental Chemistry Health, Toxicology and Mutagenesis Pollution Medicine

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