NDLI: Phenol degradation by Fenton-like process

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Phenol degradation by Fenton-like process

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Sarmento, Antover Panazzolo Romualdo, Lincoln Lucílio Borges, Alisson Carraro de Matos, Antonio Teixeira
Description	Country affiliation: Brazil Author Affiliation: Sarmento AP ( Civil Engineering Department, Federal University of Goiás, Catalão, Brazil. antoverps@ufg.br.); Borges AC ( Agricultural Engineering Department, Federal University of Viçosa, Viçosa, Brazil.); de Matos AT ( Agricultural Engineering Department, Federal University of Viçosa, Viçosa, Brazil.); Romualdo LL ( Chemistry Department, Federal University of Goiás, Catalão, Brazil.)
Abstract	The main objective of this study was to investigate the optimum conditions for the Fenton-like process on phenol degradation, using $Mn^{2+}$ as a supporting catalyst in the Fenton reaction. The effect of the independent factors $[H_{2}O_{2}],$ $[Fe^{2+}],$ $[Mn^{2+}]$ and t (reaction time) was evaluated on the efficiency of phenol degradation at two pHs (3 and 5). The experimental arrangement adopted was the Box-Behnken delineation, with the phenol concentration after the treatments suggested as response variable. At less acidic pH (5), regardless of $[Mn^{2+}],$ it was observed that the conventional Fenton process was the most efficient alternative, considering the optimum condition: $2.65 mmol L^{-1}$ for $[H_{2}O_{2}],$ $0.36 mmol L^{−1}$ for $[Fe^{2+}],$ and 90 min for t. It was observed that the addition of $Mn^{2+}$ helped the phenol degradation at more acidic pH (3), obtaining the optimum condition: $6.17 mmol L^{−1}$ for $[H_{2}O_{2}],$ $0.36 mmol L^{−1}$ for $[Fe^{2+}],$ $1.09 mmol L^{−1}$ for $[Mn^{2+}],$ and 90 min for t.
ISSN	09441344
Issue Number	18
Journal	Environmental Science and Pollution Research
Volume Number	23
e-ISSN	16147499
Language	English
Publisher	Springer
Publisher Date	2016-09-01
Publisher Place	Germany
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Discipline Environmental Science Discipline Environmental Chemistry
Content Type	Text
Resource Type	Article
Subject	Environmental Chemistry Health, Toxicology and Mutagenesis Pollution Medicine

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