NDLI: Solar-driven photocatalytic treatment of diclofenac using immobilized TiO2-based zeolite composites.

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Solar-driven photocatalytic treatment of diclofenac using immobilized TiO2-based zeolite composites.

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Suligoj, Andraz Salaeh, Subhan Fanetti, Mattia Kete, Marko Kovacic, Marin Dionysiou, Dionysios D. Kusic, Hrvoje Bozic, Ana Loncaric Stangar, Urska Lavrencic
Description	Country affiliation: Croatia Author Affiliation: Kovacic M ( Faculty of Chemical Engineering and Technology, University of Zagreb, Marulicev trg 19, HR-10000, Zagreb, Croatia.); Salaeh S ( Faculty of Chemical Engineering and Technology, University of Zagreb, Marulicev trg 19, HR-10000, Zagreb, Croatia.); Kusic H ( Faculty of Chemical Engineering and Technology, University of Zagreb, Marulicev trg 19, HR-10000, Zagreb, Croatia. hkusic@fkit.hr.); Suligoj A ( Laboratory for Environmental Research, University of Nova Gorica, Vipavska 13, SI-5000, Nova Gorica, Slovenia.); Kete M ( Laboratory for Inorganic Chemistry and Technology, National Institute of Chemistry, Hajdrihova 19, SI-1001, Ljubljana, Slovenia.); Fanetti M ( Laboratory for Environmental Research, University of Nova Gorica, Vipavska 13, SI-5000, Nova Gorica, Slovenia.); Stangar UL ( Materials Research Laboratory, University of Nova Gorica, Vipavska 11c, SI-5270, Ajdovscina, Slovenia.); Dionysiou DD ( Laboratory for Environmental Research, University of Nova Gorica, Vipavska 13, SI-5000, Nova Gorica, Slovenia.); Bozic AL ( Environmental Engineering and Science Program, University of Cincinnati, Cincinnati, OH, 45221-0012, USA.)
Abstract	The study is aimed at evaluating the potential of immobilized TiO2-based zeolite composite for solar-driven photocatalytic water treatment. In that purpose, TiO2-iron-exchanged zeolite (FeZ) composite was prepared using commercial Aeroxide TiO2 P25 and iron-exchanged zeolite of ZSM5 type, FeZ. The activity of TiO2-FeZ, immobilized on glass support, was evaluated under solar irradiation for removal of diclofenac (DCF) in water. TiO2-FeZ immobilized in a form of thin film was characterized for its morphology, structure, and composition using scanning electron microscopy/energy-dispersive x-ray spectroscopy (SEM/EDX). Diffuse reflectance spectroscopy (DRS) was used to determine potential changes in band gaps of prepared TiO2-FeZ in comparison to pure TiO2. The influence of pH, concentration of hydrogen peroxide, FeZ wt% within the composite, and photocatalyst dosage on DCF removal and conversion efficiency by solar/TiO2-FeZ/H2O2 process was investigated. TiO2-FeZ demonstrated higher photocatalytic activity than pure TiO2 under solar irradiation in acidic conditions and presence of H2O2.
ISSN	09441344
Issue Number	18
Journal	Environmental Science and Pollution Research
Volume Number	23
e-ISSN	16147499
Language	English
Publisher	Springer
Publisher Date	2016-09-01
Publisher Place	Germany
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Discipline Environmental Science Discipline Environmental Chemistry
Content Type	Text
Resource Type	Article
Subject	Environmental Chemistry Health, Toxicology and Mutagenesis Pollution Medicine

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