NDLI: Mixed rare-earth effects in (Sm/Gd)/sub 2/(Fe/Si)/sub 17/ intermetallics

Content Provider	IEEE Xplore Digital Library
Author	Marasinghe, G.K. Priyantha, W. Kamaraju, K. James, W.J. Yelon, W.B. Dubenko, I. Hill, P. Ali, N. Ellouze, M. l'Heritier, P.
Copyright Year	1965
Abstract	The effects of mixing samarium and gadolinium on the crystallographic and magnetic properties of Sm/sub y/Gd/sub 2-y/Fe/sub 17-x/Si/sub x/ (x=0, 0.33, 1.67) intermetallics have been investigated using X-ray diffraction techniques and SQUID and vibrating magnetometer measurements. The Sm/sub y/Gd/sub 2-y/Fe/sub 17-x/Si/sub x/ samples, except for the sample with x=3 and y=1, crystallized in the rhombohedral Th/sub 2/Zn/sub 17/-structure with little or no impurities. For a given silicon content (fixed x), the unit volume and saturation magnetization increases at the approximate average rates of 4 /spl Aring//sup 3/ and 24 emu/g per substituted samarium atom, respectively. The Curie temperature (T/sub c/) for a given silicon content, on the other hand, decreases with increasing samarium content at an average rate of 30-40/spl deg/C per substitution. The affect of substituting silicon for iron on T/sub c/ is more marked, with T/sub c/ increasing at a rate of almost 70/spl deg/C per silicon substitution at low silicon concentrations. For a given samarium content (fixed y), the unit cell volume and saturation magnetization decreases at approximate rates of 5 /spl Aring//sup 3/ and 9 emu/g per substituted silicon atom, respectively. X-ray diffraction studies of magnetically aligned powders indicate that the easy direction of magnetization is in the basal plane of the rhombohedral unit cell. All of the samples were found to have very little magnetic anisotropy with no apparent dependence of the anisotropy on the samarium or silicon content. The 340/spl deg/C T/sub c/ measured for the SmGdFe/sub 14/Si/sub 3/ sample is unusually high for these intermetallics and its XRD pattern is indicative of a phase other than the rhombohedral Th/sub 2/Zn/sub 17/-type.
Sponsorship	IEEE Magnetics Society
Starting Page	2599
Ending Page	2602
Page Count	4
File Size	77756
File Format	PDF
ISSN	00189464
Volume Number	37
Issue Number	4
Language	English
Publisher	Institute of Electrical and Electronics Engineers, Inc. (IEEE)
Publisher Date	2001-07-01
Publisher Place	U.S.A.
Access Restriction	One Nation One Subscription (ONOS)
Rights Holder	Institute of Electrical and Electronics Engineers, Inc. (IEEE)
Subject Keyword	Silicon Samarium Iron Saturation magnetization Intermetallic X-ray diffraction Zinc Magnetic anisotropy Crystallography Magnetic properties
Content Type	Text
Resource Type	Article
Subject	Electronic, Optical and Magnetic Materials Electrical and Electronic Engineering

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