NDLI: Synthesis, structural elucidation and spectroscopic analysis of 3a,8b-dihydroxy-4-oxo-1H,2H,3H,3aH,4H,8bH-indeno[1,2-d]imidazolidin-2-iminium chloride.

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Green synthesis of gold nanoparticles using Trigonella foenum-graecum and its size-dependent catalytic activity.

Elaborated studies for the ligitional behavior of thiouracil derivative towards Ni(II), Pd(II), Pt(IV), Cu(II) and UO2 ² ions.

Speciation of arsenic (III) and arsenic (V) based on quenching of CdS quantum dots fluorescence using hybrid sequential injection-stopped flow injection gas-diffusion system.

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Investigations of g factors for the ²E state of V²â º ions in Al2O3 crystals.

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Computational studies of 1,2-disubstituted benzimidazole derivatives.

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Synthesis, structural elucidation and spectroscopic analysis of 3a,8b-dihydroxy-4-oxo-1H,2H,3H,3aH,4H,8bH-indeno[1,2-d]imidazolidin-2-iminium chloride.

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Uma Devi, T. Priya, S. Selvanayagam, S. Ravikumar, K. Anitha, K.
Description	Country affiliation: India Author Affiliation: Uma Devi T ( Department of Physics, Government Arts College for Women, Pudukkottaii 622 001, India. kavin_shri@yahoo.co.in)
Abstract	Ninhydrin guanidinium chloride (3a,8b-dihydroxy-4-oxo-1H,2H,3H,3aH,4H,8bH-indeno [1,2-d]imidazolidin-2-iminium chloride) a semiorganic crystal was synthesized. The structure was determined using X-ray single crystal technique. Comparisons between the FT-IR spectrum of ninhydrin guanidinium chloride with ninhydrin were made. Melting point was found using thermal measurements. The molecular geometry, vibrational frequencies and Mulliken charges of the compound in the ground state have been calculated by the density functional theory (DFT) method with 3-21G(d,p) basis set and theoretical frequencies were compared with the experimental FT-IR spectrum. Besides, molecular electrostatic potential (MEP), frontier molecular orbitals (FMO) analysis, natural bond orbitals (NBO) and thermodynamic properties at various temperatures of the compound were investigated by theoretical calculations.
ISSN	13861425
Volume Number	97
e-ISSN	18733557
Journal	Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Language	English
Publisher	Elsevier
Publisher Date	2012-11-01
Publisher Place	Great Britain (UK)
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Imidazolidines Chemistry Chemical Synthesis Imines Indenes Crystallization Crystallography, X-ray Hydrogen Bonding Kinetics Models, Molecular Molecular Conformation Spectroscopy, Fourier Transform Infrared Static Electricity Thermodynamics Thermogravimetry Vibration Journal Article Research Support, Non-u.s. Gov't Discipline Spectroscopy
Content Type	Text
Resource Type	Article
Subject	Spectroscopy Atomic and Molecular Physics, and Optics Analytical Chemistry Instrumentation

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