NDLI: Three-Phase Catalytic System of $H_{2}O,$ Ionic Liquid, and $VOPO_{4}–SiO_{2}$ Solid Acid for Conversion of Fructose to 5-Hydroxymethylfurfural

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Three-Phase Catalytic System of $H_{2}O,$ Ionic Liquid, and $VOPO_{4}–SiO_{2}$ Solid Acid for Conversion of Fructose to 5-Hydroxymethylfurfural

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Three-Phase Catalytic System of $H_{2}O,$ Ionic Liquid, and $VOPO_{4}–SiO_{2}$ Solid Acid for Conversion of Fructose to 5-Hydroxymethylfurfural

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Tian, Chengcheng Zhu, Xiang Chai, Song-Hai Wu, Zili Binder, Andrew Brown, Suree Li, Lin Luo, Huimin Guo, Yanglong Dai, Sheng
Description	Author Affiliation: Tian C ( Key Laboratory for Advanced Materials, Research Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai 200237 (China))
Abstract	Efficient transformation of biomass-derived feedstocks to chemicals and fuels remains a daunting challenge in utilizing biomass as alternatives to fossil resources. A three-phase catalytic system, consisting of an aqueous phase, a hydrophobic ionic-liquid phase, and a solid-acid catalyst phase of nanostructured vanadium phosphate and mesostructured cellular foam (VPO–MCF), is developed for efficient conversion of biomass-derived fructose to 5-hydroxymethylfurfural (HMF). HMF is a promising, versatile building block for production of value-added chemicals and transportation fuels. The essence of this three-phase system lies in enabling the isolation of the solid-acid catalyst from the aqueous phase and regulation of its local environment by using a hydrophobic ionic liquid, 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide $([BMIM][Tf_{2}N]).$ This system significantly inhibits the side reactions of HMF with $H_{2}O$ and leads to 91 mol % selectivity to HMF at 89 % of fructose conversion. The unique three-phase catalytic system opens up an alternative avenue for making solid-acid catalyst systems with controlled and locally regulated microenvironment near catalytically active sites by using a hydrophobic ionic liquid
File Format	HTM / HTML
ISSN	18645631
Issue Number	6
Volume Number	7
e-ISSN	1864564X
Journal	ChemSusChem
Language	English
Publisher	Wiley-VCH
Publisher Date	2014-06-01
Publisher Place	Germany
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Ionic Liquids Water Research Support, U.s. Gov't, Non-p.h.s. Research Support, Non-u.s. Gov't Discipline Sustainable Chemistry Furaldehyde Fructose Journal Article Vanadium Compounds Chemistry Imidazoles Silicon Dioxide Catalysis Analogs & Derivatives
Content Type	Text
Resource Type	Article
Subject	Energy Environmental Chemistry Materials Science Chemical Engineering

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Efficient catalytic conversion of fructose into 5-hydroxymethylfurfural in ionic liquids at room temperature.

Catalytic conversion of carbohydrates into 5-hydroxymethylfurfural by germanium(IV) chloride in ionic liquids.

Enhanced conversion of carbohydrates to the platform chemical 5-hydroxymethylfurfural using designer ionic liquids.

Efficient and selective dehydration of fructose to 5-hydroxymethylfurfural catalyzed by Brønsted-acidic ionic liquids.

The effect of imidazolium ionic liquid on the dehydration of fructose to 5-hydroxymethylfurfural, and a room temperature catalytic system.

Acid-Catalyzed Dehydration of Fructose into 5-Hydroxymethylfurfural by Cellulose-Derived Amorphous Carbon

Nafion-resin-modified mesocellular silica foam catalyst for 5-hydroxymethylfurfural production from D-fructose.

Conversion of fructose and glucose into 5-hydroxymethylfurfural with lignin-derived carbonaceous catalyst under microwave irradiation in dimethyl sulfoxide-ionic liquid mixtures.

The First Molecular Level Monitoring of Carbohydrate Conversion to 5-Hydroxymethylfurfural in Ionic Liquids. $B_{2}O_{3}—An$ Efficient Dual-Function Metal-Free Promoter for Environmentally Benign Applications

Three-Phase Catalytic System of $H_{2}O,$ Ionic Liquid, and $VOPO_{4}–SiO_{2}$ Solid Acid for Conversion of Fructose to 5-Hydroxymethylfurfural

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Three-Phase Catalytic System of $H_{2}O,$ Ionic Liquid, and $VOPO_{4}–SiO_{2}$ Solid Acid for Conversion of Fructose to 5-Hydroxymethylfurfural