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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Straathof, Natan J. W. Gemoets, Hannes P. L. Wang, Xiao Schouten, Jaap C. Hessel, Volker Noël, Timothy |
| Description | Author Affiliation: Straathof NJ ( Department of Chemical Engineering and Chemistry, Micro Flow Chemistry & Process Technology, Eindhoven University of Technology, Den Dolech 2, 5612 AZ Eindhoven (The Netherlands).) |
| Abstract | Trifluoromethylated and perfluoroalkylated heterocycles are important building blocks for the synthesis of numerous pharmaceutical products, agrochemicals and are widely applied in material sciences. To date, trifluoromethylated and perfluoroalkylated hetero-aromatic systems can be prepared utilizing visible light photoredox catalysis methodologies in batch. While several limitations are associated with these batch protocols, the application of microflow technology could greatly enhance and intensify these reactions. A simple and straightforward photocatalytic trifluoromethylation and perfluoroalkylation method has been developed in continuous microflow, using commercially available photocatalysts and microflow components. A selection of five-membered hetero-aromatics were successfully trifluoromethylated (12â examples) and perfluoroalkylated (5â examples) within several minutes (8-20â min). |
| File Format | HTM / HTML |
| ISSN | 18645631 |
| Issue Number | 6 |
| Volume Number | 7 |
| e-ISSN | 1864564X |
| Journal | ChemSusChem |
| Language | English |
| Publisher | Wiley-VCH |
| Publisher Date | 2014-06-01 |
| Publisher Place | Germany |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Organometallic Compounds Research Support, Non-u.s. Gov't Chemistry Light Discipline Sustainable Chemistry Heterocyclic Compounds Catalysis Hydrocarbons, Fluorinated Alkylation Journal Article Photochemical Processes |
| Content Type | Text |
| Resource Type | Article |
| Subject | Energy Environmental Chemistry Materials Science Chemical Engineering |
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