NDLI: $Fe_{3}O_{4}/Carbon$ Hybrid Nanoparticle Electrodes for High-Capacity Electrochemical Capacitors

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$Fe_{3}O_{4}/Carbon$ Hybrid Nanoparticle Electrodes for High-Capacity Electrochemical Capacitors

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$Fe_{3}O_{4}/Carbon$ Hybrid Nanoparticle Electrodes for High-Capacity Electrochemical Capacitors

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Lee, Jun Seop Shin, Dong Hoon Jun, Jaemoon Lee, Choonghyeon Jang, Jyongsik
Description	Author Affiliation: Lee JS ( School of Chemical and Biological Engineering, College of Engineering, Seoul National University, 599 Gwanangno, Gwanakgu, Seoul, 151-742 (Korea), Fax: (+82) 2-888-1604.)
Abstract	$Fe_{3}O_{4}/carbon$ hybrid nanoparticles (FeCHNPs) were fabricated using dual-nozzle electrospraying, vapor deposition polymerization (VDP), and carbonization. FeOOH nanoneedles decorated with polypyrrole (PPy) nanoparticles (FePNPs) were fabricated by electrospraying pristine PPy mixed with $FeCl_{3}$ solution, followed by heating stirring reaction. A PPy coating was then formed on the FeOOH nanoneedles through a VDP process. FeCHNPs were produced through carbonization of PPy and FeOOH phase transitions. These hybrid carbon nanoparticles (NPs) were used to build electrodes of electrochemical capacitors. The specific capacitance of the FeCHNPs was $455 F g^{−1},$ which is larger than that of pristine PPy NPs $(105 F g^{−1})$ or other hybrid PPy NPs. Furthermore, the FeCHNP-based capacitors exhibited better cycle stability during charge–discharge cycling than other hybrid NP capacitors. This is because the carbon layer on the $Fe_{3}O_{4}$ surface formed a protective coating, preventing damage to the electrode materials during the charge–discharge processes. This fabrication technique is an effective approach for forming stable carbon/metal oxide nanostructures for energy storage applications.
File Format	HTM / HTML
ISSN	18645631
Issue Number	6
Journal	ChemSusChem
Volume Number	7
e-ISSN	1864564X
Language	English
Publisher	Wiley-VCH
Publisher Date	2014-06-01
Publisher Place	Germany
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Nanoparticles Electrodes Electric Power Supplies Chemistry Ferrosoferric Oxide Discipline Sustainable Chemistry Electric Capacitance Carbon Journal Article
Content Type	Text
Resource Type	Article
Subject	Energy Environmental Chemistry Materials Science Chemical Engineering

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