NDLI: Removal of $BrO_{3}^{−}$ from drinking water samples using newly developed agricultural waste-based activated carbon and its determination by ultra-performance liquid chromatography-mass spectrometry

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Removal of $BrO_{3}^{−}$ from drinking water samples using newly developed agricultural waste-based activated carbon and its determination by ultra-performance liquid chromatography-mass spectrometry

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Removal of $BrO_{3}^{−}$ from drinking water samples using newly developed agricultural waste-based activated carbon and its determination by ultra-performance liquid chromatography-mass spectrometry

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	ALOthman, Zeid A. Naushad, Mu Turki, Turki M. AlSohaimi, Ibrahim Ali, Rahmat Khan, Mohammad R. Rodriguez-Reinoso, Francisco
Description	Country affiliation: Saudi Arabia Author Affiliation: Naushad M ( Department of Chemistry, College of Science, Bldg. #5, King Saud University, Riyadh, Saudi Arabia. shad81@rediffmail.com.); Khan MR ( Department of Chemistry, College of Science, Bldg. #5, King Saud University, Riyadh, Saudi Arabia.); ALOthman ZA ( Department of Chemistry, College of Science, Bldg. #5, King Saud University, Riyadh, Saudi Arabia.); AlSohaimi I ( Department of Chemistry, College of Science, Bldg. #5, King Saud University, Riyadh, Saudi Arabia.); Rodriguez-Reinoso F ( Laboratorio de Materiales Avanzados, Departamento de Química Inorganica, Universidad de Alicante, Apartado 99, 03080, Alicante, Spain.); Turki TM ( Department of Chemistry, College of Science, Bldg. #5, King Saud University, Riyadh, Saudi Arabia.); Ali R ( Department of Chemistry, College of Science, Bldg. #5, King Saud University, Riyadh, Saudi Arabia.)
Abstract	Activated carbon was prepared from date pits via chemical activation with $H_{3}PO_{4}.$ The effects of activating agent concentration and activation temperature on the yield and surface area were studied. The optimal activated carbon was prepared at 450 °C using 55 % $H_{3}PO_{4}.$ The prepared activated carbon was characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, thermogravimetric-differential thermal analysis, and Brunauer, Emmett, and Teller (BET) surface area. The prepared date pit-based activated carbon (DAC) was used for the removal of bromate $(BrO_{3}^{−}).$ The concentration of $BrO_{3}^{−}$ was determined by ultra-performance liquid chromatography-mass tandem spectrometry (UPLC-MS/MS). The experimental equilibrium data for $BrO_{3}^{−}$ adsorption onto DAC was well fitted to the Langmuir isotherm model and showed maximum monolayer adsorption capacity of $25.64 mg g^{−1}.$ The adsorption kinetics of $BrO_{3}^{−}$ adsorption was very well represented by the pseudo-first-order equation. The analytical application of DAC for the analysis of real water samples was studied with very promising results.
ISSN	09441344
Issue Number	20
Volume Number	22
e-ISSN	16147499
Journal	Environmental Science and Pollution Research
Language	English
Publisher	Springer
Publisher Date	2015-10-01
Publisher Place	Germany
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Agriculture Bromates Analysis Isolation & Purification Charcoal Chemistry Drinking Water Waste Products Water Purification Methods Adsorption Chromatography, High Pressure Liquid Kinetics Spectroscopy, Fourier Transform Infrared Tandem Mass Spectrometry Temperature Water Pollutants, Chemical Journal Article Research Support, Non-u.s. Gov't Discipline Environmental Science Discipline Environmental Chemistry
Content Type	Text
Resource Type	Article
Subject	Environmental Chemistry Health, Toxicology and Mutagenesis Pollution Medicine

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