NDLI: Nickel ethylene tetrathiolate polymers as nanoparticles: a new synthesis for future applications?

Content Provider	Springer Nature Link
Author	Faulmann, Christophe Chahine, Joe Jacob, Kane Coppel, Yannick Valade, Lydie Caro, Dominique
Copyright Year	2013
Abstract	Coordination polymers (CP) based on the ethylene tetrathiolate ligand (C$_{2}$S$_{4}$)$^{4−}$ and Ni$^{2+}$, and previously isolated as insoluble conductive powders are grown as nanoparticles (NP) using ionic liquid (IL) as stabilizing agent. The time of addition of the IL determines the morphology, and consequently the properties of the CP. The smaller (10–20 nm) and soluble NP are obtained when IL is present at the complexation step. The mechanism of growth of NP is studied. The NP size is sensitive to the amount of IL and to the reaction temperature. NPs are studied by TEM/EDX, DLS, liquid- and solid-state NMR, and conductivity.
Starting Page	1
Ending Page	18
Page Count	18
File Format	PDF
ISSN	13880764
Journal	Journal of Nanoparticle Research
Volume Number	15
Issue Number	4
e-ISSN	1572896X
Language	English
Publisher	Springer Netherlands
Publisher Date	2013-03-26
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Nanoparticles Molecular conductors Metal ethylene tetrathiolate Microscopy NMR Nanotechnology Inorganic Chemistry Characterization and Evaluation of Materials Physical Chemistry Optics, Optoelectronics, Plasmonics and Optical Devices
Content Type	Text
Resource Type	Article
Subject	Chemistry Nanoscience and Nanotechnology Atomic and Molecular Physics, and Optics Condensed Matter Physics Bioengineering Modeling and Simulation

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