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| Content Provider | Royal Society of Chemistry (RSC) |
|---|---|
| Author | Li, Fengting Zhang, Bingru Tang, Rongzhi Liu, Sijia Xu, Ran |
| Copyright Year | 2015 |
| Abstract | Chitosan (CS)/poly(vinyl alcohol) (PVA) nanofibrous membranes have inherently poor mechanical strength. To improve the mechanical strength of these membranes, nanocrystalline cellulose (NCC) prepared by a simplified method was added to the former system. The results showed that the tensile strength of the membrane with 5% NCC addition was 370% higher than that of the membrane without NCC. Horseradish peroxidase (HRP) was immobilized on the membrane through covalent binding with HRP previously activated with 1,1′-carbonyldiimidazole, and the maximum enzyme loading was approximately 384 mg g−1. The physical, chemical properties of immobilized HRP and its application in 3,3′,5,5′-tetrabromobisphenol (TBBPA) removal were examined. The results showed that HRP immobilized on CS/PVA–NCC membranes showed greater stability and reusability than free HRP and the membrane without NCC. The former also exhibited an effective performance (95.9% removal, 3 h) for TBBPA removal under the optimum conditions (pH 7, 35 °C). The results showed that HRP immobilized on NCC-incorporated CS/PVA membranes could be used to remove brominated flame-retardants, especially TBBPA from wastewater. Thus, these membranes have potential industrial applications. |
| Starting Page | 64091 |
| Ending Page | 64097 |
| Page Count | 7 |
| File Format | HTM / HTML PDF |
| ISSN | 20462069 |
| Volume Number | 5 |
| Issue Number | 79 |
| Journal | RSC Advances |
| DOI | 10.1039/c5ra09090c |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Access Restriction | Open |
| Subject Keyword | Vinyl alcohol Enzyme HRP Cellulose Ultimate tensile strength Horseradish peroxidase Covalent bond Carbonyldiimidazole Chitosan Wastewater NCC |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Chemical Engineering |
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