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| Content Provider | PubMed Central |
|---|---|
| Author | Lv, Ruitao Li, Qing Botello-méndez, Andrés R. Hayashi, Takuya Wang, Bei Berkdemir, Ayse Hao, Qingzhen Elías, Ana Laura Cruz Silva, Rodolfo Gutiérrez, Humberto R. Kim, Yoong Ahm Muramatsu, Hiroyuki Zhu, Jun Endo, Morinobu Terrones, Humberto Charlier, Jean-christophe Pan, Minghu Terrones, Mauricio |
| Copyright Year | 2012 |
| Abstract | Graphene is a two-dimensional network in which sp2-hybridized carbon atoms are arranged in two different triangular sub-lattices (A and B). By incorporating nitrogen atoms into graphene, its physico-chemical properties could be significantly altered depending on the doping configuration within the sub-lattices. Here, we describe the synthesis of large-area, highly-crystalline monolayer N-doped graphene (NG) sheets via atmospheric-pressure chemical vapor deposition, yielding a unique N-doping site composed of two quasi-adjacent substitutional nitrogen atoms within the same graphene sub-lattice (N2 AA). Scanning tunneling microscopy and spectroscopy (STM and STS) of NG revealed the presence of localized states in the conduction band induced by N2 AA-doping, which was confirmed by ab initio calculations. Furthermore, we demonstrated for the first time that NG could be used to efficiently probe organic molecules via a highly improved graphene enhanced Raman scattering. |
| Related Links | http://dx.doi.org/10.1038/srep00586 |
| Starting Page | 586 |
| File Format | |
| ISSN | 20452322 |
| e-ISSN | 20452322 |
| Journal | Scientific Reports |
| Volume Number | 2 |
| Language | English |
| Publisher | Nature Publishing Group |
| Publisher Date | 2012-08-01 |
| Access Restriction | Open |
| Rights Holder | Nature Publishing Group |
| Subject Keyword | Science and technology Research in Higher Education |
| Content Type | Text |
| Resource Type | Article |
| Subject | Multidisciplinary |
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