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| Content Provider | IEEE Xplore Digital Library |
|---|---|
| Author | Pankow, J.W. Glick, S.H. |
| Copyright Year | 2006 |
| Description | Author affiliation: Nat. Renewable Energy Lab., Golden, CO (Pankow, J.W.; Glick, S.H.) |
| Abstract | Flexible polymer substrates coated with inorganic oxide moisture barriers are a potential replacement for glass backsheets in thin-film PV (photovoltaic) modules. Silicon oxynitride $(SiO_{x}N_{y$ ) deposited by plasma enhanced chemical vapor deposition (PECVD) on polyethylene terephthalate (PET) represents one potential new backsheet candidate. Barrier deposition runs at NREL have included a nitrogen-rich plasma pretreatment prior to barrier deposition with the intention of cleaning the PET surface and enhancing adhesion of the SiO $_{x}N_{y}$ barrier film to PET; however, test coupons of PET/barrier/EVA/TPE failed after damp-heat exposure. (EVA is ethylene vinyl acetate and TPE is Tedlar-PET-EVA). PET substrates exposed to plasma conditions similar to those used in pretreatment were examined by X-ray photoelectron spectroscopy (XPS) to reveal that new low molecular weight PET fragments were created at the PET surface. These fragments are responsible for barrier/PET interfacial failure and barrier transfer to the EVA encapsulant side following damp heat exposure |
| Sponsorship | IEEE Electron Devices Soc |
| Starting Page | 2250 |
| Ending Page | 2253 |
| File Size | 356736 |
| Page Count | 4 |
| File Format | |
| ISBN | 1424400163 |
| DOI | 10.1109/WCPEC.2006.279620 |
| Language | English |
| Publisher | Institute of Electrical and Electronics Engineers, Inc. (IEEE) |
| Publisher Date | 2006-05-07 |
| Publisher Place | USA |
| Access Restriction | Subscribed |
| Rights Holder | Institute of Electrical and Electronics Engineers, Inc. (IEEE) |
| Subject Keyword | Positron emission tomography Polymer films Substrates Plasma chemistry Moisture Glass Photovoltaic systems Solar power generation Silicon Chemical vapor deposition |
| Content Type | Text |
| Resource Type | Article |
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