NDLI: Synthesis and electronic properties of a pentafluoroethyl-derivatized nickel pincer complex

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Synthesis and electronic properties of a pentafluoroethyl-derivatized nickel pincer complex

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Ren, Peng Madhira, Venkata N. Hu, Xile Vicic, David A. Vechorkin, Oleg
Description	Author Affiliation: Madhira VN ( Department of Chemistry, University of Hawaii, 2545 McCarthy Mall, Honolulu, HI 96822, USA.)
Abstract	The synthesis of a bis(amino)amide nickel pincer complex bearing a perfluoroethyl ligand was effected by reaction of the corresponding nickel chloride complex with cesium fluoride and trimethyl(pentafluoroethyl)silane . Electrochemical experiments revealed that the oxidation of the $LNi–C_{2}F_{5}$ complex occurs at the same potential as the LNi–Cl derivative, but reduction of the $LNi–C_{2}F_{5}$ complex occurs at slightly more positive potentials. The similarity of the electrochemical data was corroborated by density functional theory (DFT), which predicts that the energies of the HOMOs (HOMO = highest occupied molecular orbital) and LUMOs (LUMO = lowest unoccupied molecular orbital) of the $LNi–C_{2}F_{5}$ and LNi–Cl complexes are equal in magnitude. DFT also revealed that the HOMOs of the bis(amino)amide nickel pincer complexes are primarily ligand in character, while the LUMOs are predominantly metal in character, supporting redox-activity with this ligand .
ISSN	14779226
Issue Number	26
Journal	Dalton Trans.
Volume Number	41
e-ISSN	13645447
Language	English
Publisher	Royal Society of Chemistry
Publisher Date	2012-07-14
Publisher Place	Great Britain (UK)
Access Restriction	Subscribed
Subject Keyword	Chemistry
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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