NDLI: Study of an S = 1 $Ni^{II}$ pincer electrocatalyst precursor for aqueous hydrogen production based on paramagnetic $^{1}H$ NMR

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Study of an S = 1 $Ni^{II}$ pincer electrocatalyst precursor for aqueous hydrogen production based on paramagnetic $^{1}H$ NMR

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Luthy, Kurt M. Habib, Fatemah Murugesu, Muralee Batista, Victor S. Paulson, Eric K. Konezny, Steven J. Luca, Oana R. Crabtree, Robert H.
Description	Author Affiliation: Luca OR ( Department of Chemistry, Yale University, P.O. Box 208107, New Haven, CT 06520-8107, USA.)
Abstract	A tridentate NNN $Ni^{II}$ complex, shown to be an electrocatalyst for aqueous $H_{2}$ production at low overpotentials, is studied by using temperature-dependent paramagnetic $^{1}H$ NMR . The NMR $T_{1}$ relaxation rates, temperature dependence of the chemical shifts, and dc SQUID magnetic susceptibility are correlated to DFT chemical shifts and compared with the properties of a diamagnetic Zn analogue complex. The resulting characterization provides an unambiguous assignment of the six proton environments in the meridionally coordinating tridentate NNN ligand . The demonstrated NMR/DFT methodology should be valuable in the search for appropriate ligands to optimize the reactivity of 3d metal complexes bound to attract increasing attention in catalytic applications.
ISSN	14779226
Issue Number	24
Journal	Dalton Trans.
Volume Number	42
e-ISSN	13645447
Language	English
Publisher	Royal Society of Chemistry
Publisher Date	2013-06-28
Publisher Place	Great Britain (UK)
Access Restriction	Subscribed
Subject Keyword	Chemistry
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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