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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Ward, Jonathan S. Moir, James Fairlamb, Ian J. S. Lynam, Jason M. |
| Description | Author Affiliation: Ward JS ( Department of Chemistry, University of York, York (UK), Fax: (+44) 1904-322516) |
| Abstract | The first visible-light-activated carbon-monoxide-releasing molecule (CO-RM) to exhibit a potent effect against Escherichia coli is described. The easily prepared tryptophan-derived manganese-containing complex (TryptoCORM) released 1.4 moles of CO at 465 nm, and 2 moles at 400 nm. A comprehensive synthetic, mechanistic and microbiological study into the behaviour of TryptoCORM is reported. The complex is thermally stable (i.e., does not release CO in solution in the absence of light), shows low toxicity against mammalian cells and releases tryptophan on photoinduced degradation, all of which point to TryptoCORM being therapeutically viable. |
| ISSN | 09476539 |
| e-ISSN | 15213765 |
| Journal | Chemistry - A European Journal |
| Issue Number | 46 |
| Volume Number | 20 |
| Language | English |
| Publisher | Wiley-VCH;ChemPubSoc Europe |
| Publisher Date | 2014-11-10 |
| Publisher Place | Germany |
| Access Restriction | Open |
| Subject Keyword | Anti-Bacterial Agents Chemistry Carbon Monoxide Administration & Dosage Coordination Complexes Escherichia Coli Drug Effects Manganese Tryptophan Analogs & Derivatives Animals Pharmacology Cell Line Escherichia Coli Infections Drug Therapy Mice Models, Molecular Research Support, Non-U.S. Gov't |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Catalysis |
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