NDLI: Photoinduced Carbon Monoxide Release from Half-Sandwich Iron(II) Carbonyl Complexes by Visible Irradiation: Kinetic Analysis and Mechanistic Investigation

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Photoinduced Carbon Monoxide Release from Half-Sandwich Iron(II) Carbonyl Complexes by Visible Irradiation: Kinetic Analysis and Mechanistic Investigation

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Liu, Xiaoming Jiang, Xiujuan Chen, Limei Wang, Xiu Xiao, Zhiyin Long, Li
Description	Author Affiliation: Jiang X ( College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing (P. R. China), Fax: (+86) 573-8364-3937.); Chen L ( School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou (P. R. China).); Wang X ( College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing (P. R. China), Fax: (+86) 573-8364-3937.); Long L ( College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing (P. R. China), Fax: (+86) 573-8364-3937.); Xiao Z ( College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing (P. R. China), Fax: (+86) 573-8364-3937.); Liu X ( College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing (P. R. China), Fax: (+86) 573-8364-3937. xiaoming.liu@mail.zjxu.edu.cn.)
Abstract	Three half-sandwich iron(II) complexes, $[Fe(η^{5}-Cp)(cis-CO)_{2}X]$ $(X^{−}=Cl^{−},$ $Br^{−},$ $I^{−}),$ were synthesized and characterized. The kinetics of the CO-releasing behaviour of these complexes upon illumination by visible irradiation in various media was investigated. Our results indicated that the CO release was significantly affected by the auxiliary ligands. Of the three light sources used (blue, green, and red), blue light exhibited the highest efficiency. In the photoinduced CO release, the solvents and exogenous nucleophiles in the media were involved, which allowed their CO-releasing reaction to comply with pseudo first-order model rather than the characteristic zero-order model for a photochemical reaction. In aqueous media $(D_{2}O),$ an intermediate bearing the core of $\{Fe^{II}(cis-CO)_{2}\}$ involving cleavage of cyclopentadiene was detected. Despite the non-absorption of the red light, its illumination combined with nucleophilic substitution did cause considerable CO release. Assessment of the cytotoxicity of the three complexes indicated that they showed good biocompatibility.
ISSN	09476539
e-ISSN	15213765
Journal	Chemistry - A European Journal
Issue Number	37
Volume Number	21
Language	English
Publisher	Wiley-VCH;ChemPubSoc Europe
Publisher Date	2015-09-07
Publisher Place	Germany
Access Restriction	Open
Subject Keyword	Chemistry
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

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