NDLI: Acute toxicity of ionic liquids for three freshwater organisms: Pseudokirchneriella subcapitata, Daphnia magna and Danio rerio.

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Acute toxicity of ionic liquids for three freshwater organisms: Pseudokirchneriella subcapitata, Daphnia magna and Danio rerio.

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Pretti, Carlo Chiappe, Cinzia Baldetti, Ilaria Brunini, Sara Monni, Gianfranca Intorre, Luigi
Description	Country affiliation: Italy Author Affiliation: Pretti C ( Dipartimento di Patologia Animale, Profilassi ed Igiene degli Alimenti, Università di Pisa, Viale delle Piagge 2, Pisa, Italy. cpretti@vet.unipi.it)
Abstract	The static acute toxicities of 18 ionic liquids (ILs) were determined for three representative freshwater organisms, the cladoceran Daphnia magna, the green alga Pseudokirchneriella subcapitata (formerly known as Selenastrum capricornutum), and the fish Danio rerio (formerly known as zebrafish). The test kit compounds contained three widely used ILs (1-butyl-3-methylimidazolium bis(triflimide), [bmim][Tf(2)N], butylpyridinium bis(triflimide), [bpy][Tf(2)N], and N,N-methylbutylpyrrolidinium bis(triflimide), [bmpyrr][Tf(2)N]) and 15 less common salts. These latter comprised a range of five anions, four positively charged head groups (ammonium, morpholinium, thiophenium, and sulfonium), five 1-methyl-3-alkyl imidazolium derivatives bearing a specific functional group on the longer alkyl chain (Cl, OH, or (CH(3))(3)Si) and three imidazolium derivatives characterized by the presence of a hydrogen atom on the imidazolium nitrogen ('Brønsted acidic imidazolium'-based ILs). Generally, long-chain ammonium salts showed higher toxicity to algae, cladocerans, and fish, whereas very low toxicities characterized sulfonium- and morpholinium-based ILs. In imidazolium-based ILs, the substitution of one or two carbon atoms of the longer alkyl chain with a more electronegative atom (chlorine or oxygen) reduced the acute toxicity for algae and cladocerans. Low toxicity also characterized the 'Brønsted acidic imidazolium'-based ILs. Structural information for a rational designer of safer ILs can be obtained from these studies.
File Format	HTM / HTML
ISSN	01476513
Issue Number	4
Volume Number	72
e-ISSN	10902414
Journal	Ecotoxicology and Environmental Safety
Language	English
Publisher	Elsevier
Publisher Date	2009-05-01
Publisher Place	Netherlands
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Discipline Environmental Sciences Chlorophyta Physiology Daphnia Ions Toxicity Zebrafish Animals Dose-response Relationship, Drug Fresh Water Lethal Dose 50 Organic Chemicals Structure-activity Relationship Journal Article Research Support, Non-u.s. Gov't
Content Type	Text
Resource Type	Article
Subject	Pollution Health, Toxicology and Mutagenesis Public Health, Environmental and Occupational Health

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