NDLI: A Cyclometalated Ir(III) Complex Containing N-naphthyl Picolinamide Ancillary Ligand

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Proceedings of the National Academy of Sciences, India Section A: Physical Sciences : Volume 84, Issue 1, March 2014

Proceedings of the National Academy of Sciences, India Section A: Physical Sciences : Volume 83

Proceedings of the National Academy of Sciences, India Section A: Physical Sciences : Volume 82

A Cyclometalated Ir(III) Complex Containing N-naphthyl Picolinamide Ancillary Ligand

Content Provider	Springer Nature Link
Author	Chandrasekhar, Vadapalli Mahanti, Bani
Copyright Year	2014
Abstract	The reaction of the cyclometalated chloro-bridged iridium(III) dimer, [(ppy)$_{2}$ Ir(μ-Cl)]$_{2}$ (ppy = 2-phenyl pyridine) with N-naphthyl picolinamide (LH) in the presence of sodium methoxide afforded a neutral heteroleptic monomer [Ir(ppy)$_{2}$L] (1). The crystal structure of 1 reveals that the ligand, in its deprotonated form, binds to the iridium center as a N,O donor. The photophysical properties reveal that 1 is a weakly emissive complex (515, 538 nm) when excited at 450 nm. DFT calculations were carried out to understand the photophysical properties.A cyclometalated iridium(III) complex [Ir(ppy)$_{2}$L] (1) (LH = N-naphthyl picolinamide) where L functions as N,O chelating donor has been synthesized and structurally characterized. 1 is weakly emissive (515, 538 nm) when excited at 450 nm.
Starting Page	115
Ending Page	120
Page Count	6
File Format	PDF
ISSN	03698203
Journal	Proceedings of the National Academy of Sciences, India Section A: Physical Sciences
Volume Number	84
Issue Number	2
e-ISSN	22501762
Language	English
Publisher	Springer India
Publisher Date	2014-03-11
Publisher Place	India
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Applied and Technical Physics Absorption DFT Emission Atomic, Molecular, Optical and Plasma Physics Cyclometalated Ir(III) compound Quantum Physics N-naphthyl picolinamide Physics
Content Type	Text
Resource Type	Article
Subject	Physics and Astronomy Biochemistry, Genetics and Molecular Biology

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