NDLI: Ruthenium Carbonyl Complexes with 4-R-Benzaldehyde Thiosemicarbazone as an Ancillary Ligand: Synthesis and, Structural, Spectral and Electrochemical Properties

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Ruthenium Carbonyl Complexes with 4-R-Benzaldehyde Thiosemicarbazone as an Ancillary Ligand: Synthesis and, Structural, Spectral and Electrochemical Properties

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Ruthenium Carbonyl Complexes with 4-R-Benzaldehyde Thiosemicarbazone as an Ancillary Ligand: Synthesis and, Structural, Spectral and Electrochemical Properties

Content Provider	Springer Nature Link
Author	Bhattacharya, Samaresh Paul, Piyali Deb, Ria
Copyright Year	2016
Abstract	Reaction of 4-R-benzaldehyde thiosemicarbazone (denoted as HL-R; where H stands for the dissociable acidic proton and R (R = OCH$_{3}$, CH$_{3}$, H, Cl and NO$_{2}$) for the substituents) with [Ru(CO)$_{2}$Cl$_{2}$]$_{n}$ in toluene in the presence of triethylamine affords a group of yellow complexes of the type [Ru(CO)$_{2}$(L-R)$_{2}$]. Structure of [Ru(CO)$_{2}$(L-NO$_{2}$)] has been determined by X-ray crystallography. In [Ru(CO)$_{2}$(L-R)$_{2}$] complexes, the thiosemicarbazone ligands are bound to the metal center as monoanionic bidentate N,S-donor forming four-membered chelate ring. All the complexes are diamagnetic, and show characteristic $^{1}$H NMR signals. The [Ru(CO)$_{2}$(L-R)$_{2}$] complexes show intense absorptions in the visible and ultraviolet regions, which have been analyzed by DFT calculations. Cyclic voltammetry on the complexes shows two irreversible oxidations near 0.87 and 1.28 V versus SCE, and an irreversible reduction around −1.24 V versus SCE.
Starting Page	551
Ending Page	559
Page Count	9
File Format	PDF
ISSN	03698203
Journal	Proceedings of the National Academy of Sciences, India Section A: Physical Sciences
Volume Number	86
Issue Number	4
e-ISSN	22501762
Language	English
Publisher	Springer India
Publisher Date	2016-10-08
Publisher Place	New Delhi
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Spectral and electrochemical properties Applied and Technical Physics Atomic, Molecular, Optical and Plasma Physics Ruthenium carbonyl complex Benzaldehyde thiosemicarbazone Quantum Physics Physics Crystal structure
Content Type	Text
Resource Type	Article
Subject	Physics and Astronomy Biochemistry, Genetics and Molecular Biology

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