NDLI: Studies on the Coordination Behavior of Methanesulfonate in Zinc(II) Based Two and Three Dimensional Supramolecular Assemblies

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Proceedings of the National Academy of Sciences, India Section A: Physical Sciences : Volume 84, Issue 1, March 2014

Proceedings of the National Academy of Sciences, India Section A: Physical Sciences : Volume 83

Proceedings of the National Academy of Sciences, India Section A: Physical Sciences : Volume 82

Studies on the Coordination Behavior of Methanesulfonate in Zinc(II) Based Two and Three Dimensional Supramolecular Assemblies

Content Provider	Springer Nature Link
Author	Singh, Rohit Molloy, Kieran C. Kociok Köhn, Gabriele Shankar, Ravi
Copyright Year	2014
Abstract	The zinc complexes, [Zn(OS(O)$_{2}$Me)$_{2}$(H$_{2}$O)$_{2}$]$_{n}$ 1 and [Zn(OS(O)$_{2}$Me)$_{2}$(H$_{2}$O)$_{4}$]$_{n}$ 2 are obtained as hydrolysis products of the homoleptic zincate salt, [Et$_{4}$N]$_{2}$[Zn(OS(O)$_{2}$Me)$_{4}$]. The reaction of 2 with 4,4′-bipyridine (4,4′-bipy) in dry methanol yields [{Zn(4,4′-bipy)(H$_{2}$O)$_{4}$}(OS(O)$_{2}$Me)$_{2}$]$_{n}$, 3. The structure of 1 adopts one-dimensional polymeric motif by virtue of bridging bidentate mode of methanesulfonate groups while 2 is a molecular entity with monodentate sulfonate groups directly bonded to the zinc atom. The coordination framework of 3 is composed of infinite arrays of cationic [ZnO$_{4}$N$_{2}$] octahedra with methanesulfonate anions being located in the secondary coordination sphere. The sulfonate group in 1–3 acts as a hub for O–H…O type hydrogen bonds and assists the formation of two-/three-dimensional supramolecular assemblies.
Starting Page	157
Ending Page	163
Page Count	7
File Format	PDF
ISSN	03698203
Journal	Proceedings of the National Academy of Sciences, India Section A: Physical Sciences
Volume Number	84
Issue Number	2
e-ISSN	22501762
Language	English
Publisher	Springer India
Publisher Date	2014-03-02
Publisher Place	India
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Zincate dianion Applied and Technical Physics Methanesulfonate Atomic, Molecular, Optical and Plasma Physics Quantum Physics Supramolecular assembly Physics Hydrogen bond
Content Type	Text
Resource Type	Article
Subject	Physics and Astronomy Biochemistry, Genetics and Molecular Biology

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