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| Content Provider | Springer Nature Link |
|---|---|
| Author | Silvetti, Margherita Castaldi, Paola Garau, Giovanni Demurtas, Daniela Deiana, Salvatore |
| Copyright Year | 2015 |
| Abstract | Here, we report on the ability of two different water treatment residues, a Fe-based (Fe-WTR) and an Al-based (Al-WTR) ones, to accumulate Cd(II) and Zn(II) from aqueous solutions at different pH values (pH 4.5, 5.5, and 7.0). Fe-WTR showed a greater Zn(II) and Cd(II) sorption capacity than Al-WTR at all the pH values investigated, in particular at pH 7.0 (e.g., ∼0.200 and ∼0.100 mmol g$^{−1}$ of Me(II) sorbed by Fe- and Al-WTR at pH 7.0, respectively). The greater capacity of the Fe-WTR to accumulate Me(II) seems to be linked to its higher content of iron and manganese ions and to its higher CEC value compared to Al-WTR. The role of the inorganic and organic fractions of WTRs in metal sorption was also assessed. A higher affinity of Cd(II) with respect to Zn(II) toward functional groups of the organic matter of both WTRs was observed, while Zn(II) showed a stronger association with the inorganic phases. The sorption of both metal ions appeared mainly governed by the formation of inner-sphere surface complexes with the inorganic and organic phases of WTRs, as suggested by the sequential extraction data. |
| Starting Page | 1 |
| Ending Page | 13 |
| Page Count | 13 |
| File Format | |
| ISSN | 00496979 |
| Journal | Water, Air, and Soil Pollution |
| Volume Number | 226 |
| Issue Number | 9 |
| e-ISSN | 15732932 |
| Language | English |
| Publisher | Springer International Publishing |
| Publisher Date | 2015-08-28 |
| Publisher Place | Cham |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Fe- and Al-WTRs Cd(II) and Zn(II) Sorption isotherms Sequential extraction FT-IR spectroscopy Environment Water Quality/Water Pollution Atmospheric Protection/Air Quality Control/Air Pollution Soil Science & Conservation Hydrogeology Climate Change/Climate Change Impacts |
| Content Type | Text |
| Resource Type | Article |
| Subject | Ecological Modeling Environmental Chemistry Pollution Environmental Engineering Water Science and Technology |
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