NDLI: Catalytic hydrodechlorination reaction of chlorophenols by Pd nanoparticles supported on graphene

Content Provider	Springer Nature Link
Author	Chang, Wonghil Kim, Hojun Lee, Ga Young Ahn, Byoung Joon
Copyright Year	2015
Abstract	Chlorophenols are widely used as industrial chemicals such as herbicides, insecticides, wood preservatives, and disinfectants. However, chlorophenols are very toxic materials and they have become the cause of current environmental issues. Hydrodechlorination (HDC) reaction is a more environmentally friendly removal method of chlorophenols than other methods. In this paper, Pd–modified graphene was prepared and applied to HDC reaction. Pd supported on graphene (refer to Pd/G) was prepared using the recently reported microwave irradiation method. The Pd(II)/GO was made by impregnation methods of palladium precursors in solution phase and was subsequently reduced to Pd/G by microwave irradiation. The morphological and chemical structure of the Pd/G was characterized by XRD, SEM, ICP-MS, EDS, and TEM. It was found that the graphene-based Pd catalyst showed the highest catalytic performance among Pd/Y, Pd/MCM-41, and Pd/G catalysts. This is attributed to the smaller particle size and higher dispersions of Pd nanoparticles on the graphene surface. The catalytic HDC of chlorophenols was investigated. For HDC reaction, 100 ppm solution of chlorophenols such as 4-chlorophenol, six isomers of dichlorophenol, and 2,3,5-trichlorophenol in isopropanol was treated with catalyst and base, such as Na$_{2}$CO$_{3}$ and K$_{2}$CO$_{3}$, under a hydrogen gas at ambient pressure. The progress of the chlorophenol decomposition was analyzed with GC. All chlorophenols were completely decomposed within 2 h in the 3 % Pd/G catalyst. The reaction pathway of chlorophenols was elucidated from the conversion of chlorophenols and selectivities of products. The reuse of the catalyst was also studied. The performance of the recycled catalyst in HDC reaction up to six successive runs was observed.
Starting Page	71
Ending Page	82
Page Count	12
File Format	PDF
ISSN	09226168
Journal	Research on Chemical Intermediates
Volume Number	42
Issue Number	1
e-ISSN	15685675
Language	English
Publisher	Springer Netherlands
Publisher Date	2015-12-29
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Hydrodechlorination Chlorophenol Dichlorophenols Trichlorophenol Pd–graphene Catalysis Physical Chemistry Inorganic Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Gas phase hydrotreatment of chlorophenols over Pd catalysts as an alternative route to cyclohexanone

Kinetic Analysis of 4-Chlorophenol Hydrodechlorination Catalyzed by Rh Nanoparticles Based on the Two-Step Reaction and Langmuir–Hinshelwood Mechanisms

Highly Uniform Pd Nanoparticles Supported on g-C3N4 for Efficiently Catalytic Suzuki–Miyaura Reactions

A Highly Active Pd on Ni–B Bimetallic Catalyst for Liquid-Phase Hydrodechlorination of 4-Chlorophenol Under Mild Conditions

Polyacrylamide-g-Reduced Graphene Oxide Supported Pd Nanoparticles as a Highly Efficient Catalyst for Suzuki–Miyaura Reactions in Water

Influence of Pd Precursor and Method of Preparation on Hydrodechlorination Activity of Alumina Supported Palladium Catalysts

Active carbon-supported nickel–palladium catalysts for hydrodechlorination of 1,2-dichloroethane and 1,1,2-trichloroethene

Synthesis and Catalytic Studies of Uniform Os & Os–Pd Nanoparticles Supported on MWNTs

Flame-made Alumina Supported Pd–Pt Nanoparticles: Structural Properties and Catalytic Behavior in Methane Combustion

Catalytic hydrodechlorination reaction of chlorophenols by Pd nanoparticles supported on graphene

Similar Documents

Gas phase hydrotreatment of chlorophenols over Pd catalysts as an alternative route to cyclohexanone

Kinetic Analysis of 4-Chlorophenol Hydrodechlorination Catalyzed by Rh Nanoparticles Based on the Two-Step Reaction and Langmuir–Hinshelwood Mechanisms

Highly Uniform Pd Nanoparticles Supported on g-C3N4 for Efficiently Catalytic Suzuki–Miyaura Reactions

A Highly Active Pd on Ni–B Bimetallic Catalyst for Liquid-Phase Hydrodechlorination of 4-Chlorophenol Under Mild Conditions

Polyacrylamide-g-Reduced Graphene Oxide Supported Pd Nanoparticles as a Highly Efficient Catalyst for Suzuki–Miyaura Reactions in Water

Influence of Pd Precursor and Method of Preparation on Hydrodechlorination Activity of Alumina Supported Palladium Catalysts

Active carbon-supported nickel–palladium catalysts for hydrodechlorination of 1,2-dichloroethane and 1,1,2-trichloroethene

Synthesis and Catalytic Studies of Uniform Os & Os–Pd Nanoparticles Supported on MWNTs

Flame-made Alumina Supported Pd–Pt Nanoparticles: Structural Properties and Catalytic Behavior in Methane Combustion

Catalytic hydrodechlorination reaction of chlorophenols by Pd nanoparticles supported on graphene