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Effect of alkali metal salts on decomposition of ionic liquid like organic salt

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Effect of alkali metal salts on decomposition of ionic liquid like organic salt

Content Provider	Springer Nature Link
Author	Jo, Gyeong Cheol Goh, Eun Mee Baek, Seung Wook Cho, Sung June
Copyright Year	2015
Abstract	N $^{1}$,N $^{1}$,N $^{2}$,N $^{2}$-tetramethylethane-1,2-diamine-based ionic salts (TMEDA), N $^{1}$,N $^{1}$,N $^{1}$,N $^{2}$,N $^{2}$,N $^{2}$-hexamethylethane-1,2-diaminium dicyanamide (HMEDA-(DCA)$_{2}$) were prepared following the quaternization and subsequent ion exchange. The chemical structure of the HMEDA-(DCA)$_{2}$ was confirmed using $^{13}$C NMR spectrum and elemental analysis. The corresponding viscosity of its 60 wt% solution was found to be lower than 5 cP at room temperature, which was critical for propellant application. The ignition delay of 40 wt% HMEDA-(DCA)$_{2}$ solution was decreased to 20–30 ms dramatically using alkali metal salts, Li(CH$_{3}$COO), Mg(CH$_{3}$COO)$_{2}$, and Ca(CH$_{3}$COO)$_{2}$ as a co-catalyst when white fume nitric acid was utilized as an oxidizer.
Starting Page	201
Ending Page	209
Page Count	9
File Format	PDF
ISSN	09226168
Journal	Research on Chemical Intermediates
Volume Number	42
Issue Number	1
e-ISSN	15685675
Language	English
Publisher	Springer Netherlands
Publisher Date	2015-11-03
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Ionic salts Hypergolic Catalytic decomposition Alkali metal additive Catalysis Physical Chemistry Inorganic Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry

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