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| Content Provider | Springer Nature Link |
|---|---|
| Author | Li, Ji Li, Shanshan Wang, Li Xu, Shichong Liu, Mei Li, Haibo |
| Copyright Year | 2015 |
| Abstract | CoAl$_{ x }$Fe$_{2−x }$O$_{4}$/SiO$_{2}$ (0 ≤ x ≤ 1.0) nanocomposite films were synthesized on Si (100) substrates by sol–gel spin-coating method. The effects of Al$^{3+}$ content and annealing temperature on the structure and magnetic properties of the samples were investigated by X-ray diffraction, atomic force microscopy, field emission scanning electron microscopy, and vibrating sample magnetometer. The results showed CoAl$_{ x }$Fe$_{2−x }$O$_{4}$ in the films could be crystallized with a single phase spinel structure after being annealed. When the Al$^{3+}$ contents x increased from 0 to 1.0, the lattice constants of CoAl$_{ x }$Fe$_{2−x }$O$_{4}$ nanoparticles in the films decreased from 0.8370 to 0.8251 nm, the average crystallite sizes decreased from 37 to 25 nm, and the in-plane and out-of-plane coercivity of the films decreased from 258 and 315 kA/m to 46 and 63 kA/m, respectively. As the annealing temperatures rose from 800 to 1150 °C, the lattice constants of CoAl$_{0.2}$Fe$_{1.8}$O$_{4}$ nanoparticles in the films decreased from 0.8369 to 0.8352 nm, while the average crystallite sizes increased from 7 to 63 nm. And the CoAl$_{0.2}$Fe$_{1.8}$O$_{4}$ nanoparticles in the films had obvious (111) preferred orientation at annealing temperature of 1150 °C. The in-plane and out-of-plane coercivity of CoAl$_{0.2}$Fe$_{1.8}$O$_{4}$/SiO$_{2}$ nanocomposite film annealed at 1100 °C showed the maximum values of 198 and 259 kA/m, respectively. The critical sizes of single-domain and superparamagnetism for CoAl$_{0.2}$Fe$_{1.8}$O$_{4}$ nanoparticles in the films at room temperature were also estimated. |
| Starting Page | 3088 |
| Ending Page | 3094 |
| Page Count | 7 |
| File Format | |
| ISSN | 09574522 |
| Journal | Journal of Materials Science: Materials in Electronics |
| Volume Number | 27 |
| Issue Number | 3 |
| e-ISSN | 1573482X |
| Language | English |
| Publisher | Springer US |
| Publisher Date | 2015-11-27 |
| Publisher Place | New York |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Optical and Electronic Materials Characterization and Evaluation of Materials |
| Content Type | Text |
| Resource Type | Article |
| Subject | Atomic and Molecular Physics, and Optics Biomaterials Biophysics Condensed Matter Physics Electronic, Optical and Magnetic Materials Bioengineering Electrical and Electronic Engineering Biomedical Engineering |
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