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Alkynylation of graphene via the Sonogashira C–C cross-coupling reaction on fluorographene† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8cc08492k
| Content Provider | Semantic Scholar |
|---|---|
| Author | Chronopoulos, Demetrios D. Medved', Miroslav Błoński, Piotr Nováček, Zdeněk Jakubec, Petr Tomanec, Ondrej Bakandritsos, Aristides Novotná, Veronika Zbořil, Radek Otyepka, Michal |
| Copyright Year | 2019 |
| Abstract | We report successful grafting of alkynyl groups onto graphene via the Sonogashira reaction between fluorographene and terminal alkynes. Theoretical calculations revealed that fluorographene can efficiently bind and oxidize the palladium catalyst on electrophilic sites activated by fluorine atoms. This paves the way towards conductive and mechanically robust 3D covalent networks. |
| Starting Page | 1088 |
| Ending Page | 1091 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c8cc08492k |
| PubMed reference number | 30620024 |
| Journal | Medline |
| Volume Number | 55 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c8/cc/c8cc08492k/c8cc08492k1.pdf |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |