NDLI: Solid-state Suzuki–Miyaura cross-coupling reactions: olefin-accelerated C–C coupling using mechanochemistry† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc02185j

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Solid-state Suzuki–Miyaura cross-coupling reactions: olefin-accelerated C–C coupling using mechanochemistry† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc02185j

Content Provider	Semantic Scholar
Author	Seo, Tamae Ishiyama, Tatsuo Kubota, Koji Ito, Hajime
Copyright Year	2019
Abstract	The Suzuki-Miyaura cross-coupling reaction is one of the most reliable methods for the construction of carbon-carbon bonds in solution. However, examples for the corresponding solid-state cross-coupling reactions remain scarce. Herein, we report the first broadly applicable mechanochemical protocol for a solid-state palladium-catalyzed organoboron cross-coupling reaction using an olefin additive. Compared to previous studies, the newly developed protocol shows a substantially broadened substrate scope. Our mechanistic data suggest that olefin additives might act as dispersants for the palladium-based catalyst to suppress higher aggregation of the nanoparticles, and also as stabilizer for the active monomeric Pd(0) species, thus facilitating these challenging solid-state C-C bond forming cross-coupling reactions.
Starting Page	8202
Ending Page	8210
Page Count	9
File Format	PDF HTM / HTML
DOI	10.1039/c9sc02185j
PubMed reference number	31857886
Journal	Medline
Volume Number	10
Alternate Webpage(s)	http://www.rsc.org/suppdata/c9/sc/c9sc02185j/c9sc02185j1.pdf
Alternate Webpage(s)	https://ftp.ncbi.nlm.nih.gov/pub/pmc/oa_pdf/87/ed/SC-010-C9SC02185J.PMC6836942.pdf
Alternate Webpage(s)	https://doi.org/10.1039/c9sc02185j
Journal	Chemical science
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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