Loading...
Please wait, while we are loading the content...
Similar Documents
Visible light-mediated gold-catalysed carbon(sp2)–carbon(sp) cross-coupling† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c5sc03025k
| Content Provider | Semantic Scholar |
|---|---|
| Author | Kim, Suhong Rojas-Martín, Jaime Toste, F. Dean |
| Copyright Year | 2016 |
| Abstract | A dual photoredox and gold-catalysed cross-coupling reaction of alkynyltrimethylsilanes and aryldiazonium tetrafluoroborates is described. The reaction proceeds through visible-light mediated oxidative addition of aryldiazoniums, transmetalation of alkynyltrimethylsilanes and aryl-alkynyl reductive elimination. Exclusive selectivity for silyl-substituted alkynes is observed, with no reactivity observed for terminal alkynes. |
| Starting Page | 85 |
| Ending Page | 88 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c5sc03025k |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/articlepdf/2016/sc/c5sc03025k?page=search |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/articlepdf/2016/sc/c5sc03025k |
| Alternate Webpage(s) | http://www.cchem.berkeley.edu/toste/publications/CS_2016_7_85.pdf |
| Alternate Webpage(s) | http://www.cchem.berkeley.edu/~toste/publications/CS_2016_7_85.pdf |
| PubMed reference number | 29861967 |
| Alternate Webpage(s) | https://doi.org/10.1039/c5sc03025k |
| Journal | Medline |
| Volume Number | 7 |
| Journal | Chemical science |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
