NDLI: Nickel-catalyzed C–N bond activation: activated primary amines as alkylating reagents in reductive cross-coupling† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc00783k

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Nickel-catalyzed C–N bond activation: activated primary amines as alkylating reagents in reductive cross-coupling† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc00783k

Content Provider	Semantic Scholar
Author	Yue, Huifeng Zhu, Chen Shen, Li Fu Geng, Qiuyang Hock, Katharina J. Yuan, Tingting Cavallo, Luigi Rueping, Magnus
Copyright Year	2019
Abstract	Nickel-catalyzed reductive cross coupling of activated primary amines with aryl halides under mild reaction conditions has been achieved for the first time. Due to the avoidance of stoichiometric organometallic reagents and external bases, the scope regarding both coupling partners is broad. Thus, a wide range of substrates, natural products and drugs with diverse functional groups are tolerated. Moreover, experimental mechanistic investigations and density functional theory (DFT) calculations in combination with wavefunction analysis have been performed to understand the catalytic cycle in more detail.
Starting Page	4430
Ending Page	4435
Page Count	6
File Format	PDF HTM / HTML
DOI	10.1039/C9SC00783K
PubMed reference number	31057770
Journal	Medline
Volume Number	10
Alternate Webpage(s)	https://pubs.rsc.org/en/content/articlepdf/2019/sc/c9sc00783k?page=search
Alternate Webpage(s)	https://pubs.rsc.org/en/content/articlepdf/2019/sc/c9sc00783k
Alternate Webpage(s)	http://www.rsc.org/suppdata/c9/sc/c9sc00783k/c9sc00783k1.pdf
Alternate Webpage(s)	https://doi.org/10.1039/C9SC00783K
Journal	Chemical science
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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