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Darstellung und Charakterisierung von Bis(trichlorsilyl)phenylamin und 2,2,4,4-TetrachIor-1,3-diphenyl-[ 1,3,2,4]diazadisiletidin / Preparation and Characterization of Bis(trichlorosilyl)phenylamine and 2,2,4,4-Tetrachloro-1,3-diphenyl-[ 1,3,2,4]diazadisiletidine
| Content Provider | Semantic Scholar |
|---|---|
| Author | Bzik, Stefan Jansen, Martin |
| Copyright Year | 2001 |
| Abstract | Abstract Bis(trichlorsilyl)phenylamine (1) and 2,2,4,4-tetrachlor-l,3-diphenyl-[l,3,2,4]diazadisiletid-ine (2) have been synthesized as potential precursors for the preparation of porous oxygen-free solids by the reaction of tetrachlorosilane with dilithiated aniline. Both compounds were characterized by crystal structure analysis. 1 crystallizes monoclinically, P2/n, a = 10.124(2), b = 12.701(2), c = 11.425(3) Å, β = 109.34(2)° and Z = 4 (R1 = 4.6%, wR2 = 11.6%, 1297 independent reflections). 2 crystallizes orthorhombically, Pbca, a = 11.42(1), b = 8.17(1), c = 17.05(1)Å, and Z = 4 (R1 = 3.7%, wR2 = 8.2%, 1923 independent reflections). Ammonolyses and polycondensation of 1 and 2 yield amorphous solids with low porosities. |
| Starting Page | 164 |
| Ending Page | 168 |
| Page Count | 5 |
| File Format | PDF HTM / HTML |
| DOI | 10.1515/znb-2001-0208 |
| Alternate Webpage(s) | http://www.znaturforsch.com/ab/v56b/56b0164.pdf |
| Alternate Webpage(s) | https://doi.org/10.1515/znb-2001-0208 |
| Volume Number | 56 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
