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Darstellung und Charakterisierung von Monoorganobismut(III)-und Bismut(III)-Derivaten von Mercaptocarbonsäuren /Preparation and Characterization of Monoorganobismuth(III) and Bismuth (III) Derivatives of Mercaptocarbonic Acids
| Content Provider | Semantic Scholar |
|---|---|
| Author | Praeckel, U. Huber, Friedo |
| Copyright Year | 1981 |
| Abstract | Abstract Cleavage of Bi-C-bonds in Ph3Bi (Ph = C6H5) by mercaptocarboxylic acids (H2Mc) depends on solvents and concentration. Ph3Bi in CHl3 and H2MC (= mercaptoacetic, 3-and 2-mercaptopropionic, 2-mercaptobenzoic acid) reacted to give Bi(Mc)(HMc); in acetone at lower concentrations PhBi(Mc) (H2Mc =2-mercaptopropionic, 2-mercaptobenzoic acid) was obtained. Me3Bi (Me = CH3) and H2Mc gave MeBi(Mc) at all concentrations used. Polymeric structures with bridging Mc-groups and four-coordinated Bi are proposed. |
| Starting Page | 70 |
| Ending Page | 73 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1515/znb-1981-0115 |
| Volume Number | 36 |
| Alternate Webpage(s) | http://zfn.mpdl.mpg.de/data/Reihe_B/36/ZNB-1981-36b-0070.pdf |
| Alternate Webpage(s) | https://doi.org/10.1515/znb-1981-0115 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |