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Darstellung und Charakterisierung substituierter Phosphinoether und -thioether / Preparation and Characterization of Substituted Phosphinoethers and -thioethers
| Content Provider | Semantic Scholar |
|---|---|
| Author | Wolfsberger, Werner Burkart, Wolfgang R. Werner, Helmut |
| Copyright Year | 1995 |
| Abstract | The (diorganophosphinopropyl)alkyl ethers 1-7 are prepared by hydrophosphination of allylalkyl ethers with secondary phosphines. The corresponding thioethers cannot be obtained in a pure state by the same route. The nucleophilic ring opening of thiirane with lithium dialkyl phosphides, followed by the reaction with ClSi(CH3)3 or Cl(CH2)2OCH3 produces the thioethers 8-12 and 16. The silylated thioethers 8, 10 and 12 react with CH3OH/H2O to give the phosphinoethyl thiols 13-15. All new compounds have been identified and characterized by elemental analyses, IR and NMR spectra. |
| Starting Page | 168 |
| Ending Page | 174 |
| Page Count | 7 |
| File Format | PDF HTM / HTML |
| DOI | 10.1515/znb-1995-0202 |
| Volume Number | 50 |
| Alternate Webpage(s) | http://zfn.mpdl.mpg.de/data/Reihe_B/50/ZNB-1995-50b-0168.pdf |
| Alternate Webpage(s) | https://doi.org/10.1515/znb-1995-0202 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
