NDLI: Hollow nanoreactors for Pd-catalyzed Suzuki–Miyaura coupling and O-propargyl cleavage reactions in bio-relevant aqueous media† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc04390f

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Hollow nanoreactors for Pd-catalyzed Suzuki–Miyaura coupling and O-propargyl cleavage reactions in bio-relevant aqueous media† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc04390f

Content Provider	Semantic Scholar
Author	Destito, Paolo Sousa-Castillo, Ana Couceiro, José R. López, Fernando Correa-Duarte, Miguel A. Mascareñas, José Luis
Copyright Year	2019
Abstract	We describe the fabrication of hollow microspheres consisting of mesoporous silica nanoshells decorated with an inner layer of palladium nanoparticles and their use as Pd-nanoreactors in aqueous media. These palladium-equipped capsules can be used to promote the uncaging of propargyl-protected phenols, as well as Suzuki-Miyaura cross-coupling, in water and at physiologically compatible temperatures. Importantly, the depropargylation reaction can be accomplished in a bioorthogonal manner in the presence of relatively high concentrations of biomolecular components and even in the presence of mammalian cells.
Starting Page	2598
Ending Page	2603
Page Count	6
File Format	PDF HTM / HTML
DOI	10.1039/c8sc04390f
PubMed reference number	30996975
Journal	Medline
Volume Number	10
Alternate Webpage(s)	https://pubs.rsc.org/en/content/articlepdf/2019/sc/c8sc04390f?page=search
Alternate Webpage(s)	https://pubs.rsc.org/en/content/articlepdf/2019/sc/c8sc04390f
Alternate Webpage(s)	http://www.rsc.org/suppdata/c8/sc/c8sc04390f/c8sc04390f2.pdf
Alternate Webpage(s)	https://doi.org/10.1039/c8sc04390f
Journal	Chemical science
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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