Loading...
Please wait, while we are loading the content...
Similar Documents
A study of the solution of tin in iron-nickel and iron-palladium alloys by Mossbauer spectroscopy
| Content Provider | Scilit |
|---|---|
| Author | Cranshaw, T. E. |
| Copyright Year | 1980 |
| Description | Journal: Journal of Physics F: Metal Physics A study of the solution of$ ^{119}$Sn in nickel-iron and palladium-iron alloys by Mossbauer spectroscopy is presented. An attractive interaction is found between Sn atoms and nickel or palladium atoms in their first-neighbour shells of 0.1 and 0.28 eV respectively. The values of the solubility of tin in 6% and 8% Ni alloys, and 1% and 2% Pd alloys are measured as a function of temperature in the ranges 520-650 degrees C and 950-1150 degrees C respectively. From the slope of the log solubility curve, a heat of formation of the precipitate $Ni_{3}Sn_{2}$ of 12 kcal per gram atom and of an unidentified PdSn compound of 33 kcal per gram atom is obtained. The presence of a Ni or Pd atom in the first-neighbour shell of a Sn atom makes the hyperfine field at$ ^{119}$sn about 21 kOe more positive; a Ni atom in the second-neighbour shell makes it 23 kOe more negative. Pd atoms in the second-neighbour shell were not observed. |
| Related Links | http://iopscience.iop.org/article/10.1088/0305-4608/10/6/031/pdf |
| Ending Page | 1340 |
| Page Count | 18 |
| Starting Page | 1323 |
| ISSN | 03054608 |
| DOI | 10.1088/0305-4608/10/6/031 |
| Journal | Journal of Physics F: Metal Physics |
| Issue Number | 6 |
| Volume Number | 10 |
| Language | English |
| Publisher | IOP Publishing |
| Publisher Date | 1980-06-01 |
| Access Restriction | Open |
| Subject Keyword | Journal: Journal of Physics F: Metal Physics Metallurgy and Metallurgical Engineering Mossbauer Spectroscopy |
| Content Type | Text |
| Resource Type | Article |
| Subject | Metals and Alloys 3100/3101 Engineering |
