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A Mossbauer study of iron precipitates in CuFe alloys
| Content Provider | Scilit |
|---|---|
| Author | Campbell, S. J. Clark, P. E. |
| Copyright Year | 1974 |
| Description | Journal: Journal of Physics F: Metal Physics The Mossbauer effect has been used in a study of CuFe alloys containing up to 4.6 at% iron over the temperature range 4.2 to 300K. It is found that face centred cubic gamma -Fe is not retained in CuFe alloys quenched sufficiently rapidly from the solid solution region but that the spectra of the solution quenched alloys are consistent with a model in which the iron atoms tend to form clusters. After allowing for the alpha -Fe content in a concentrated alloy a value of 3.1+or-0.2 at% is obtained as the solubility limit for Fe in Cu at 1000 degrees C in agreement with values obtained by other techniques. The precipitation of gamma -Fe and the subsequent development of alpha -Fe has been observed in alloys heat treated at 650 degrees C. At low temperatures gamma -Fe is known to be antiferromagnetic and a value of $T_{N}$=63+or-4K is obtained for the Neel temperature of gamma -Fe precipitates in copper and a value of 2.7+or-0.3T for the magnetic hyperfine field at 4.2K. By applying an external magnetic field of 8T at 4.2K the magnetic hyperfine spectrum of theta -Fe has been resolved in a composite spectrum. |
| Related Links | http://iopscience.iop.org/article/10.1088/0305-4608/4/7/013/pdf |
| Ending Page | 1083 |
| Page Count | 11 |
| Starting Page | 1073 |
| ISSN | 03054608 |
| DOI | 10.1088/0305-4608/4/7/013 |
| Journal | Journal of Physics F: Metal Physics |
| Issue Number | 7 |
| Volume Number | 4 |
| Language | English |
| Publisher | IOP Publishing |
| Publisher Date | 1974-07-01 |
| Access Restriction | Open |
| Subject Keyword | Journal: Journal of Physics F: Metal Physics Metallurgy and Metallurgical Engineering Condensed Matter Physics Magnetic Field Solid Solution |
| Content Type | Text |
| Resource Type | Article |
| Subject | Metals and Alloys 3100/3101 Engineering |