NDLI: Understanding the thermo-sensitivity of crystalline colloidal arrays formed by poly(styrene-co-N-isopropylacrylamide) core

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Soft Matter Vol - 8 Issue - 5

Understanding the thermo-sensitivity of crystalline colloidal arrays formed by poly(styrene-co-N-isopropylacrylamide) core–shell microspheres

Content Provider	Royal Society of Chemistry (RSC)
Author	Zhu, X. X. Bazin, Gwénaëlle
Copyright Year	2012
Abstract	Poly(styrene-co-N-isopropylacrylamide) core–shell microspheres have been synthesized by a two-step surfactant-free emulsion polymerization process. These microspheres are thermo-responsive with a clear volume phase transition around 30 °C and form crystalline colloidal arrays over a wide range of concentrations. The resulting crystalline arrays also display a response to temperature, visible through a change in the diffraction spectrum. However, the response appears to be highly dependent on the microsphere concentration. This behavior originates from a change in the short-range interactions between particles rather than from the volume change of the particles caused by the volume phase transition. Attractive van der Waals interactions increase while repulsions decrease; these changes only affect the equilibrium of concentrated samples, where the interparticle distance is sufficiently short to have an effect.
Starting Page	1909
Ending Page	1915
Page Count	7
File Format	HTM / HTML PDF
ISSN	1744683X
Volume Number	8
Issue Number	6
Journal	Soft Matter
DOI	10.1039/c1sm06344h
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Diffraction Emulsion polymerization Microparticle Van der Waals force Phase transition
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics

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