NDLI: A red emitting of manganese-doped boron carbon oxynitride (BCNO) phosphor materials: facile approach and photoluminescence properties

Content Provider	Royal Society of Chemistry (RSC)
Author	Nuryantini, Ade Y. Faryuni, Irfana D. Abdullah, Mikrajuddin Iskandar, Ferry Nuryadin, Bebeh W. Permatasari, Fitri A.
Copyright Year	2017
Abstract	BCNO (boron carbon oxynitride) phosphors have attracted attention due to their non toxicity, simple synthesis process, and high quantum efficiency. However, the tunable emission, particularly a red emission, is still challenging to achieve. In the present study, a bright red emission (emission wavelength 620 nm under 365 nm UV excitation) of a manganese-doped BCNO (BCNO:Mn) phosphor synthesized by a solid state method is reported. Without Mn-doping, the BCNO phosphor exhibited a bright blue emission that can be ascribed to the closed-shell BO− and BO2− anions that act as luminescence center. Via Mn-doping, a red emission was exhibited that can be ascribed to the 4T1(4G) → 6A1(6S) transition from a new luminescence center of Mn2+ incorporated into the BCNO host lattice. The optimum red PL properties (λem: 611 nm, λex: 365 nm) were obtained with BCNO:Mn at a molar ratio of Mn/B at 0.71% mol/mol synthesized at 550 °C. We believe that the BCNO:Mn is a promising red-emitting phosphor for white light diodes.
Starting Page	4161
Ending Page	4166
Page Count	6
File Format	HTM / HTML PDF
ISSN	20462069
Volume Number	7
Issue Number	7
Journal	RSC Advances
DOI	10.1039/c6ra27018b
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Bright Blue Boron Luminescence Carbon Wavelength Silicon oxynitride Crystal structure
Content Type	Text
Resource Type	Article
Subject	Chemistry Chemical Engineering

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