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| Content Provider | Royal Society of Chemistry (RSC) |
|---|---|
| Author | Oz, E. Demirel, S. Altin, E. Altin, S. Avci, S. Bayri, A. |
| Copyright Year | 2016 |
| Abstract | We report the results of a systematic investigation of structural, electrical transport, magnetic, and electrochemical properties of LiBxMn2−xO4 (where x = 0.0–1), synthesized via a one-step solid state reaction technique. We find that the parent compound (x = 0) has the non-stoichiometric Li1.05Mn2O4 phase and the B ions successfully incorporate the structure for x ≤ 0.5. The resistivity anomaly of the parent compound below 100 K is attributed to the antiferromagnetic correlations. The linear part of the χ−1–T data are used to calculate the effective magnetic moments and to determine the total number of Mn3+ and Mn4+ ions. Magnetization measurements show that Jahn–Teller active Mn3+ ions have high spin configuration. Average valance of Mn ions increases with increasing boron content. Electrochemical studies show improved capacity retention for x = 0.125 for 100 charge–discharge cycles. This improvement is attributed to subtle modifications in the structural and magnetic properties upon substitution. |
| Starting Page | 43823 |
| Ending Page | 43831 |
| Page Count | 9 |
| File Format | HTM / HTML PDF |
| ISSN | 20462069 |
| Volume Number | 6 |
| Issue Number | 49 |
| Journal | RSC Advances |
| DOI | 10.1039/c6ra05032h |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Access Restriction | Open |
| Subject Keyword | Electrical resistivity and conductivity Antiferromagnetism Jahn\u2013Teller effect Boron Magnetization Electrochemistry Non-stoichiometric compound Jahn |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Chemical Engineering |
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