NDLI: Energetic alliance of tetrazole-1-oxides and 1,2,5-oxadiazoles

Content Provider	Royal Society of Chemistry (RSC)
Author	Klapötke, Thomas M. Reymann, Marius Völkl, Maurus B. R. Fischer, Dennis Stierstorfer, Jörg
Copyright Year	2015
Abstract	The connection of highly endothermic heterocycles with high nitrogen as well as oxygen content is a recent trend in the development of new energetic materials in order to increase densities and stabilities. Bis(1-hydroxytetrazolyl)furazane (9) and bis(1-hydroxytetrazolyl)furoxane (10) were synthesized for the first time from dicyanofurazane and dicyanofuroxane, respectively. Several nitrogen-rich compounds (e.g. ammonium and hydroxylammonium) and metal salts thereof were prepared. Most compounds were characterized by single crystal X-ray diffraction. In addition all compounds were analyzed by vibrational spectroscopy (IR and Raman), multinuclear NMR spectroscopy, elemental analysis and DSC measurements. The heats of formation of 4, 5, 15–16, 20 and 24 were calculated using the atomization method based on CBS-4M enthalpies. With these values and the experimental (X-ray) densities several detonation parameters such as the detonation pressure, velocity, energy and temperature were computed using the EXPLO5 code (V.5.05). In addition, the sensitivities towards impact, friction and electrical discharge were tested using the BAM drop hammer and friction tester as well as a small scale electrical discharge device.
Starting Page	1619
Ending Page	1627
Page Count	9
File Format	HTM / HTML PDF
ISSN	11440546
Volume Number	39
Issue Number	3
Journal	New Journal of Chemistry
DOI	10.1039/c4nj01351d
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Endothermic process X-ray crystallography Infrared spectroscopy Oxygen Ammonium DSC CBS Furazan Pile driver Nuclear magnetic resonance spectroscopy Raman Nitrogen
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry Catalysis

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