NDLI: Facile synthesis of ZnFe<sub>2</sub>O<sub>4</sub> with inflorescence spicate architecture as anode materials for lithium-ion batteries with outstanding performance

Content Provider	Royal Society of Chemistry (RSC)
Author	Hu, Shejun Hou, Xianhua Liu, Xiang Wang, Xinyu Wu, Yuping Yao, Lingmin
Copyright Year	2015
Abstract	ZnFe2O4 with inflorescence spicate architecture has been synthesized by a facile co-precipitation method with the presence of oxalic acid. The ZnFe2O4 as an anode material with novel morphological structure was emphasized by X-ray diffraction (XRD), Fourier transform infrared spectra (FT-IR), Raman spectroscopy and so on. As an anode for LIBs, the inflorescence spicate ZnFe2O4 exhibits excellent electrochemical performance with an initial discharge capacity of 1647.2 mA h g−1, maintaining a reversible discharge capacity of 1398.1 mA h g−1 after 100 cycles at a current density of 100 mA g−1 (84.9% of the first discharge capacity) and favorable rate capacity (766 mA h g−1 at 1.2 A g−1). Such attractive performance is ascribed mainly to its unique inflorescence spicate electrode morphology, which can provide good electrical contact and conductivity, and provide a buffer medium to accommodate the volume expansion of electrode materials during the electrochemical reaction process. More importantly, this study not only provides a simple synthesis method for lithium-ion batteries, but also helps in designing novel electrode materials with high performance.
Starting Page	1943
Ending Page	1952
Page Count	10
File Format	HTM / HTML PDF
ISSN	11440546
Volume Number	39
Issue Number	3
Journal	New Journal of Chemistry
DOI	10.1039/c4nj01535e
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Infrared spectroscopy Lithium-ion battery Electrode Anode Inflorescence Fourier transform Fourier-transform infrared spectroscopy Raman spectroscopy X-ray crystallography Fourier Electrochemistry Raman Electric current Coprecipitation
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry Catalysis

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