NDLI: AgPd–MnO<sub>x</sub> supported on carbon nanospheres: an efficient catalyst for dehydrogenation of formic acid

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New Journal of Chemistry Vol - 41 Issue - 8

New Journal of Chemistry Vol - 41 Issue - 7

New Journal of Chemistry Vol - 41 Issue - 6

New Journal of Chemistry Vol - 41 Issue - 5

New Journal of Chemistry Vol - 41 Issue - 4

New Journal of Chemistry Vol - 41 Issue - 3

New Journal of Chemistry Vol - 41 Issue - 2

New Journal of Chemistry Vol - 41 Issue - 1

New Journal of Chemistry Vol -39

New Journal of Chemistry Vol -29

New Journal of Chemistry Vol -0

AgPd–MnO_x supported on carbon nanospheres: an efficient catalyst for dehydrogenation of formic acid

Content Provider	Royal Society of Chemistry (RSC)
Author	Gao, Shutao Wang, Zhi Shang, Ningzhao Wu, Qiuhua Zhou, Xin Wang, Chun Feng, Cheng Zhang, Xiaoyu
Copyright Year	2017
Abstract	Hydrogen is widely regarded as a future sustainable and clean energy feedstock. Formic acid is considered as one of the most promising hydrogen carriers. However, efficient and selective dehydrogenation from formic acid under mild conditions constitutes a major challenge because of the ease poisoning of catalysts with CO formed as an intermediate during formic acid decomposition. Here, we develop a new heterogeneous catalyst composed of bimetallic AgPd and MnOx nanoparticles immobilized on biomass-derived carbon nanospheres with well-controlled nano-morphologies. In this catalytic system, MnOx nanoparticles could act as a CO-sponge and enhance both the catalytic activity and CO-resistivity of AgPd nanoparticles. The prepared catalyst exhibits 100% H2 selectivity and excellent catalytic activity, greatly facilitating the hydrogen generation from formic acid with the turnover frequency of 3558 h−1 at 50 °C. Moreover, this new catalytic system shows very high stability, which makes it reusable. The exceptional performance of the new catalytic system presents itself as an excellent contender for efficient hydrogen production from formic acid. This work opens up a new way for the development of high-performance metal nanocatalysts.
Starting Page	3443
Ending Page	3449
Page Count	7
File Format	HTM / HTML PDF
ISSN	11440546
Volume Number	41
Issue Number	9
Journal	New Journal of Chemistry
DOI	10.1039/c6nj03873e
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Heterogeneous catalysis Hydrogen Dehydrogenation Carbon
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry Catalysis

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