NDLI: Hydrothermal synthesis of polyaniline intercalated vanadium oxide xerogel hybrid nanocomposites: effective control of morphology and structural characterization

Content Provider	Royal Society of Chemistry (RSC)
Author	Kar, Tanusree Kundu, Samapti Mukherjee, Manabendra Satpati, Biswarup Pradhan, Swapan Kumar
Copyright Year	2017
Abstract	Polyaniline (PANI) intercalated layered vanadium oxide xerogel hybrid nanocomposites have been successfully synthesized via a simple hydrothermal route. FESEM images reveal the surface morphology of fiber and rod shaped PANI/vanadium oxide xerogel (PV) nanocomposites. The fiber and rod like morphologies of the PV nanocomposite have been tailored by controlling the relative concentration in between PANI and peroxovanadic acid solution and it leads to the formation of a V2O5·nH2O xerogel. The growth mechanism of the specific morphology has been proposed on the basis of the detailed structure and microstructure characterization of nanocomposites by analyzing their XRD patterns employing Rietveld refinement and FESEM/HRTEM images. Both FTIR and XPS spectra confirm the formation of PANI/vanadium oxide xerogel nanocomposites, the presence of polyaniline and water molecules in the nanocomposites and partial reduction of V5+ to V4+. This corroborates well with the results of XRD pattern analysis. XPS spectra analysis also reveals the relative contents of V5+ and V4+ in both composites. UV-Vis spectra further confirm the formation of these nanocomposites. The growth direction of the synthesized nanorods along 〈00l〉 is confirmed by Rietveld refinement and HRTEM image analyses. The core shell structure of the composite, in which, an amorphous PANI sheath layer acts as the shell covering the crystalline V2O5·nH2O core, is confirmed from the HRTEM images. STEM-HAADF images and EDX spectra confirm the chemical composition and uniform distribution of PANI and V2O5·nH2O over the entire area of the nanocomposites. Intercalation of water and PANI layers into the V2O5·nH2O layer resulted in an orthorhombic to monoclinic structural phase transition due to a substantial increase in the interplanar spacing of the (00l) plane of orthorhombic V2O5. Atomic modeling reveals the lamellar like structure of the nanocomposite wherein PANI chains are sandwiched between double layers of VO6 octahedra. Rietveld refinement estimates the quantitative measure of intercalated V2O5·nH2O, VO2 and PANI in the composites. It is reported for the first time that the relative contents of these phases regulate the morphology of these nanocomposites.
Starting Page	3634
Ending Page	3645
Page Count	12
File Format	HTM / HTML PDF
ISSN	11440546
Volume Number	41
Issue Number	9
Journal	New Journal of Chemistry
DOI	10.1039/c7nj00372b
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Rietveld refinement Monoclinic crystal system Vanadium PANI Rietveld Polyaniline X-ray crystallography Thin-shell structure Hydrothermal circulation Discrete uniform distribution FTIR Orthorhombic crystal system Octahedron Nanocomposite Phase transition
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry Catalysis

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