NDLI: Preparation, voltammetry, coulometry and electrochemical quartz crystal gravimetry of [Os(bipy)2(PVPS)nClRu(edta)] redox polymers

Please wait, while we are loading the content...

The synthesis of an electronically asymmetric substituted poly(arylenevinylene); poly{2-(2′-ethylhexyloxy)-5-[(E)-4″-nitrostyryl]-l,4-phenyienevinylene}

Preparation, voltammetry, coulometry and electrochemical quartz crystal gravimetry of [Os(bipy)₂(PVPS)_nClRu(edta)] redox polymers

Phasmidic phases in macrocyclic liquid crystals

The influence of heteroatoms and branchings on the liquid-crystalline properties of cyclotriveratrylene derivatives

ortho-Palladated metallomesogens: the effects of structural modifications on their liquid crystalline behaviour

Synthesis and liquid-crystalline properties of novel laterally connected twins: the influence of the connecting topology and the length of the rigid core

Structure and properties of sulfonated poly [(vinylidene fluoride)–g-styrene] norous membranes porous membranes

Optical waveguide fabrication using a polymeric azine containing the 3-dodecyithiophene moiety

Structure of rhodanine cyanine dyes, spectroscopy and performance in photographic emulsions

Synthesis and spectroscopic characterisation of MoO₃ thin films

From Bi₄V₂O₁₁ to Bi₄V₂O_10.66: the V^V–V^IV transformation in the aurivillius-type framework

Ionic conductivity of SrO-Ta₂O₅ and SrO-La₂O₃-Ta₂O₅ compounds

Selectivity and composition dependence of response of gas-sensitive resistors. Part 3.—Properties of the solid solution series (CrNbO₄)_x(Sn_{1 –y},Sb_yO₂)_{1 –x}(0 x 1, y= 0,0.01, 0.05)

Preparation and characterization of perovskite-type Ln′_xLn″_1–xCoO₃ for electroceramic applications

Infrared reflection study of cofacially stacked phthalocyanines doped with iodine

EELS and photoemission study of antimony-doped Cd₂SnO₄ ceramics

Crystal structures and magnetic properties of La₂Zn_xMg_{1 –x}IrO₆

Synthesis and crystal structures of ‘Li _1.8K_0.9M_0.75Zr_2.25O_6.6’(M = Cu, Mg): a family of novel rocksalt–perovskite intergrowth phases

Molecular dynamics study of TiO₂ microclusters

Solid-state NMR characterization of β-sialons from self-propagating high-temperature synthesis

Carbothermal reduction of sillimanite

Preparation and characterization of magnesium–calcium hydroxyapatites

FTIR analysis of the surface of nanostructured aluminium nitride powder prepared via chemical synthesis

Synthesis and precise characterization of large single crystals of as-synthesized CrAPO-5, H_2.1[Cr_0.08Al_11.62P₁₂O₄₈]F_1.2·1.6TEA

Thermal behaviour of Zn–Cr layered double hydroxides with hydrotalcite-like structures containing carbonate or decavanadate

Homogeneous precipitation from solution by urea hydrolysis: a novel chemical route to the α-hydroxides of nickel and cobalt

Characterization of RuMo–SiO₂ catalysts. A comparative study before and after CO hydrogenation reaction

Processable aluminosilicate alkoxide precursors from metal oxides and hydroxides. The oxide one-pot synthesis process

Metal–insulator transition and molecular dynamics in (NH₃)K₃C₆₀

The synthesis and structure of TlSr₂NiO_{4 +δ}

Synthesis and characterization of a nanostructured gallium nitride–PMMA composite

Back cover

Back matter

Journal of Materials Chemistry Vol - 6 Issue - 7

Journal of Materials Chemistry Vol - 6 Issue - 6

Journal of Materials Chemistry Vol - 6 Issue - 5

Journal of Materials Chemistry Vol - 6 Issue - 4

Journal of Materials Chemistry Vol - 6 Issue - 3

Journal of Materials Chemistry Vol - 6 Issue - 2

Journal of Materials Chemistry Vol -5

Journal of Materials Chemistry Vol -4

Journal of Materials Chemistry Vol -3

Preparation, voltammetry, coulometry and electrochemical quartz crystal gravimetry of [Os(bipy)₂(PVPS)_nClRu(edta)] redox polymers

Content Provider	Royal Society of Chemistry (RSC)
Author	Glidle, Andrew Lindall, Charles M. Peacock, Robert D. Cole-Hamilton, David J. Crayston, Joe A.
Copyright Year	1996
Abstract	Mixed-metal polymers [Os(bipy)2(PVPS)nClRu(edta)](n= 10,15,20) have been prepared by reaction of [Os(bipy)2(PVPS)nCl]Cl coated electrodes with K[Ru(edta)(H2O)](n= 10,15,20) in solutions of various electrolytes (PVPS = polyvinylpyridine–co-styrene, 10% styrene; edta = ethylenediaminetetraacetato; bipy = 2,2′-bipyridyl). Incorporation of the [Ru(edta)]– unit and binding to the pyridine ligands of P VPS takes place with displacement of water from the coordination sphere of the Ru centre. The resulting [Os(bipy)2(PVPS)nClRu(edta)](n= 10,15,20) polymers are reasonably stable, although reduction at –0.4 V causes gradual loss of Ru centres over 1 h. Slow-scan voltammetry (5 mV s–1) of thin films in aqueous and acetonitrile solvents confirms the approximate 1:1 Os: Ru stoichiometry. Charge-transport characteristics have been investigated by chronocoulometry and rotating disk voltammetry. The behaviour of [Os(bipy)2(PVPS)nCl]X towards other anionic complexes has been investigated: [Mo(CN)8]4– and [Fe(bathophen)3]4–(bathophen = 4,7-diphenyl-l,10-phenanthrolinedisulfonate) bind electrostatically to [Os(bipy)2(PVPS)nCl]X. Ion-exchange studies of the mixed Os-Ru polymers towards complex anions and cations shows that methyl viologen (MV2+) induces a decrease in the electroactivity of the covalently bound [Ru(edta)]– units, and additionally, a decrease in the electroactivity of the Os sites. The fraction of electroactive Os sites in the thick films is increased by the presence of coordinated Ru owing to an enhanced rate of charge transport. No evidence was found that reduction of the [Ru(edta)]– units of the mixed Os-Ru polymer induces incorporation of MV2+; instead, loss of [Ru(edta)(H2O)]– from the polymer rather than MV2+ incorporation dominates. Oxidation of the [Os(bipy)2Cl]+ units of the mixed Os-Ru polymer does, however, induce incorporation of [Fe(bathophen)3]4–; alternatively, quaternization of the polymer dramatically increases its affinity for anions. It is possible to incorporate MV2+ and [Fe(bathophen)3]4– simultaneously, yielding a multiple redox polymer containing six different redox states. In aqueous 0.1 mol dm–3 NaNO3 solution in the absence of added Ru complex, quartz crystal microbalance experiments show rapid loss of the Ru complex from the polymer, leaving an Os polymer which takes up anions on oxidation. In acetonitrile solvent the stability of the attached Ru is much greater and quartz crystal microbalance experiments suggest that the mixed Os–Ru polymer shows a mass increase on Ru reduction, associated with both cation ingress and anion egress. The RuIII/II potential in acetonitrile becomes more negative, indicating stronger preferences of the polymer and cations for the oxidized Ru IIhalf of the redox couple.
Starting Page	1259
Ending Page	1269
Page Count	11
File Format	PDF
ISSN	09599428
Volume Number	6
Issue Number	8
Journal	Journal of Materials Chemistry
DOI	10.1039/JM9960601259
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Ethylenediaminetetraacetic acid Styrene Pyridine Virtual private server Voltammetry Acetonitrile Stoichiometry Paraquat Polymer Menshutkin reaction Redox Sodium nitrate Microbalance Solvent Ion
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Mass Transfer from Ion-Sensing Component-Loaded Nanoemulsions into Ion-Selective Membranes: An Electrochemical Quartz Crystal Microbalance and Thin-Film Coulometry Study.

Transport of ionic charge and solvent in poly(3-octylthiophene) films: An electrochemical quartz crystal microbalance study

Solvent effects on the electrochemical p-doping of PEDOT

Investigation of Electron Transfer byGeobacter sulfurreducensBiofilms by using an Electrochemical Quartz Crystal Microbalance

A Combined Electrochemical Quartz-Crystal Microbalance Probe Beam Deflection (EQCM-PBD) Study of Solvent and Ion Transfers at a Poly[Ni(saltMe)]-Modified Electrode During Redox Switching

Electrochemical deposition of poly(trans-[RuCl₂(4-vinylpyridine)₄]) and its reductive desorption: cyclic voltammetry and electrochemical quartz crystal microbalance studies

Electrochemical study of cerium(IV) in the presence of ethylenediaminetetraacetic acid (EDTA) and diethylenetriaminepentaacetate (DTPA) ligands

Multiple redox polymers prepared by covalent and electrostatic binding to poly(vinylpyridine-co-styrene): cooperative binding and potential-induced electrostatic binding

Investigation of Ion and Solvent Transport Accompanying Redox Reactions of Polyvmylferrocene Films Using an in situ Electrochemical Quartz Crystal Microbalance Technique

Preparation, voltammetry, coulometry and electrochemical quartz crystal gravimetry of [Os(bipy)₂(PVPS)_nClRu(edta)] redox polymers

Similar Documents

Mass Transfer from Ion-Sensing Component-Loaded Nanoemulsions into Ion-Selective Membranes: An Electrochemical Quartz Crystal Microbalance and Thin-Film Coulometry Study.

Transport of ionic charge and solvent in poly(3-octylthiophene) films: An electrochemical quartz crystal microbalance study

Solvent effects on the electrochemical p-doping of PEDOT

Investigation of Electron Transfer byGeobacter sulfurreducensBiofilms by using an Electrochemical Quartz Crystal Microbalance

A Combined Electrochemical Quartz-Crystal Microbalance Probe Beam Deflection (EQCM-PBD) Study of Solvent and Ion Transfers at a Poly[Ni(saltMe)]-Modified Electrode During Redox Switching

Electrochemical deposition of poly(trans-[RuCl2(4-vinylpyridine)4]) and its reductive desorption: cyclic voltammetry and electrochemical quartz crystal microbalance studies

Electrochemical study of cerium(IV) in the presence of ethylenediaminetetraacetic acid (EDTA) and diethylenetriaminepentaacetate (DTPA) ligands

Multiple redox polymers prepared by covalent and electrostatic binding to poly(vinylpyridine-co-styrene): cooperative binding and potential-induced electrostatic binding

Investigation of Ion and Solvent Transport Accompanying Redox Reactions of Polyvmylferrocene Films Using an in situ Electrochemical Quartz Crystal Microbalance Technique

Preparation, voltammetry, coulometry and electrochemical quartz crystal gravimetry of [Os(bipy)2(PVPS)nClRu(edta)] redox polymers

Electrochemical deposition of poly(trans-[RuCl₂(4-vinylpyridine)₄]) and its reductive desorption: cyclic voltammetry and electrochemical quartz crystal microbalance studies

Preparation, voltammetry, coulometry and electrochemical quartz crystal gravimetry of [Os(bipy)₂(PVPS)_nClRu(edta)] redox polymers