NDLI: Electrochemical deposition of poly(trans-[RuCl<sub>2</sub>(4-vinylpyridine)<sub>4</sub>]) and its reductive desorption: cyclic voltammetry and electrochemical quartz crystal microbalance studies

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Electrochemical deposition of poly(trans-[RuCl₂(4-vinylpyridine)₄]) and its reductive desorption: cyclic voltammetry and electrochemical quartz crystal microbalance studies

Ferrocenylalkylthiolate labeling of defects in alkylthiol self-assembled monolayers on gold

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Physical Chemistry Chemical Physics Vol - 9 Issue - 7

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Electrochemical deposition of poly(trans-[RuCl₂(4-vinylpyridine)₄]) and its reductive desorption: cyclic voltammetry and electrochemical quartz crystal microbalance studies

Content Provider	Royal Society of Chemistry (RSC)
Author	Glidle, Andrew Franco, César V. Crayston, Joe A. Bandeira, Merlin C. E.
Copyright Year	2007
Abstract	The electropolymerization of trans-[RuCl2(vpy)4] (vpy = 4-vinylpyridine) on Au or Pt electrodes was studied by cyclic voltammetry and the electrochemical quartz crystal microbalance (EQCM) technique. Cyclic voltammetry of the monomer in DMSO on Au shows reductions at −2.0 and −2.2 V. Potential cycling over the first wave leads to polymer formation; however, scanning over the second wave leads to desorption of the polymer. These observations were confirmed by EQCM measurements which also revealed a high polymerization efficiency. Electrolysis, EQCM and XPS measurements showed that desorption was associated with substitution of chloride ligands by DMSO when the polymer was in a highly reduced state. The film also showed reversible mass changes due to the oxidation and accompanying ingress of charge-balancing anions and solvent into the film. Measurements on the dried films revealed that large quantities of solvent are trapped in the film during the electropolymerization process.
Starting Page	1003
Ending Page	1012
Page Count	10
File Format	HTM / HTML PDF
ISSN	14639076
Volume Number	9
Issue Number	8
Journal	Physical Chemistry Chemical Physics
DOI	10.1039/b613242a
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Nanoarchitectures for lithium-ion batteries DMSO Polymerization Polymer Cyclic voltammetry Chloride Electrolysis EQCM Dimethyl sulfoxide Electrochemistry Monomer Solvent Microbalance
Content Type	Text
Resource Type	Article
Subject	Physics and Astronomy Physical and Theoretical Chemistry

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