NDLI: Furfurylamines from biomass: transaminase catalysed upgrading of furfurals

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Green Chemistry Vol - 19 Issue - 1

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Furfurylamines from biomass: transaminase catalysed upgrading of furfurals

Content Provider	Royal Society of Chemistry (RSC)
Author	Ward, John M. Subrizi, Fabiana Dunbabin, Alice Sheppard, Tom D. Hailes, Helen C.
Copyright Year	2017
Abstract	Furfural is recognised as an attractive platform molecule for the production of solvents, plastics, resins and fuel additives. Furfurylamines have many applications as monomers in biopolymer synthesis and for the preparation of pharmacologically active compounds, although preparation via traditional synthetic routes is not straightforward due to by-product formation and sensitivity of the furan ring to reductive conditions. In this work transaminases (TAms) have been investigated as a mild sustainable method for the amination of furfural and derivatives to access furfurylamines. Preliminary screening with a recently reported colorimetric assay highlighted that a range of furfurals were readily accepted by several transaminases and the use of different amine donors was then investigated. Multistep synthetic routes were required to synthesise furfurylamine derivatives for use as analytical standards, highlighting the benefits of using a one step biocatalytic route. To demonstrate the potential of using TAms for the production of furfurals, the amination of selected compounds was then investigated on a preparative scale.
Starting Page	397
Ending Page	404
Page Count	8
File Format	HTM / HTML PDF
ISSN	14639262
Volume Number	19
Issue Number	2
Journal	Green Chemistry
DOI	10.1039/c6gc02241c
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Subscribed
Subject Keyword	Furfural Biopolymer Furan Transaminase
Content Type	Text
Resource Type	Article
Subject	Environmental Chemistry Pollution

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Furfurylamines from biomass: transaminase catalysed upgrading of furfurals

Base-Free Synthesis of Furfurylamines from Biomass Furans Using Ru Pincer Complexes

Correction: High yield 5-(hydroxymethyl)furfural production from biomass sugars under facile reaction conditions: a hybrid enzyme- and chemo-catalytic technology

Targeting Valuable Chemical Commodities: Hydrazine-mediated Diels-Alder Aromatization of Biobased Furfurals.

Process for producing furan from furfural aldehyde

Reduced metal nanocatalysts for selective electrochemical hydrogenation of biomass-derived 5-(hydroxymethyl)furfural to 2,5-bis(hydroxymethyl)furan in ambient conditions.

Temperature-dependent phase behaviour of tetrahydrofuran–water alters solubilization of xylan to improve co-production of furfurals from lignocellulosic biomass

Cascade Upgrading of Biomass-Derived Furfural to γ-Valerolactone Over Zr/Hf-Based Catalysts

Production of 5-hydroxymethylfurfural and furfural by dehydration of biomass-derived mono- and poly-saccharides

Furfurylamines from biomass: transaminase catalysed upgrading of furfurals

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Furfurylamines from biomass: transaminase catalysed upgrading of furfurals

Base-Free Synthesis of Furfurylamines from Biomass Furans Using Ru Pincer Complexes

Correction: High yield 5-(hydroxymethyl)furfural production from biomass sugars under facile reaction conditions: a hybrid enzyme- and chemo-catalytic technology

Targeting Valuable Chemical Commodities: Hydrazine-mediated Diels-Alder Aromatization of Biobased Furfurals.

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Production of 5-hydroxymethylfurfural and furfural by dehydration of biomass-derived mono- and poly-saccharides

Furfurylamines from biomass: transaminase catalysed upgrading of furfurals