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| Content Provider | Royal Society of Chemistry (RSC) |
|---|---|
| Author | Zhang, Zhuoyong Wang, Jingrong Xiang, Yuhong Zhang, Zhenwei Harrington, Peter de B. |
| Copyright Year | 2014 |
| Abstract | Terahertz time-domain spectroscopy (THz-TDS) as a new non-destructive testing method has been applied to the identification of 41 official and unofficial rhubarb samples in the present work. The THz time domain spectra of rhubarb samples were preprocessed and then used to establish an identification model by using fuzzy rule-building expert systems (FuRES). The model was validated using a bootstrapped Latin-partitions (BLPs) method with 10 bootstraps and 4 Latin-partitions. The obtained results showed that the model has good predictive ability with respect to the classification accuracy of 94.8 ± 0.5% and 95.2 ± 0.1% by using the preprocessing methods of Savitzky–Golay (S–G) first derivative combined with either one of two orthogonal signal correction (OSC) methods, respectively. The proposed method showed that THz-TDS combined with chemometrics can be used to identify genuine and counterfeit Chinese herbal medicines, as well as official and unofficial rhubarb. |
| Starting Page | 7695 |
| Ending Page | 7702 |
| Page Count | 8 |
| File Format | HTM / HTML PDF |
| ISSN | 17599660 |
| Volume Number | 6 |
| Issue Number | 19 |
| Journal | Analytical Methods |
| DOI | 10.1039/c4ay00555d |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Access Restriction | Open |
| Subject Keyword | Golay Nondestructive testing Terahertz time-domain spectroscopy Rhubarb Orthogonality Savitzky OSC Chemometrics |
| Content Type | Text |
| Resource Type | Article |
| Subject | Analytical Chemistry Engineering Chemical Engineering |
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