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| Content Provider | IEEE Xplore Digital Library |
|---|---|
| Author | Koyanagi, T. Hino, K. Nagamoto, Y. Yoshitake, H. Kishimoto, K. |
| Copyright Year | 1997 |
| Description | Author affiliation: Dept. of Electr. & Electron. Eng., Yamaguchi Univ., Ube, Japan (Koyanagi, T.) |
| Abstract | We have tried to dope /spl beta/-Zn/sub 4/Sb/sub 3/ with Sn for the purpose of the p-type doping and the enhancement of phonon scattering, which further improve the thermoelectric properties of /spl beta/Zn/sub 4/Sb/sub 3/. Polycrystalline samples doped with Sn were prepared by the spark plasma sintering method. Although no other phase was observed except for /spl beta/-Zn/sub 4/Sb/sub 3/ in Sn-doped samples up to 3%, their lattice constants were not at all changed from that of bulk /spl beta/-Zn/sub 4/Sb/sub 3/, indicating that Sn was not unfortunately substituted for Sb. These results suggest that microcrystals of Sn is dispersed in grain boundary regions of /spl beta/-Zn/sub 4/Bb/sub 3/. The Seebeck coefficient was almost unchanged, and the electrical conductivity was slightly decreased by doping /spl beta/-Zn/sub 4/Sb/sub 3/ with Sn, indicating that Sn does not act as a dopant. On the other hand the thermal conductivity was lowered from 8.66mW/cmK of the non-doped sample to 6.88mW/cmK of the 3% Sn-doped sample at room temperature. This lowering of the thermal conductivity was considered to be due to the point defect phonon scattering induced by inclusions of Sn. |
| Starting Page | 463 |
| Ending Page | 466 |
| File Size | 390411 |
| Page Count | 4 |
| File Format | |
| ISBN | 0780340574 |
| ISSN | 10942734 |
| DOI | 10.1109/ICT.1997.667186 |
| Language | English |
| Publisher | Institute of Electrical and Electronics Engineers, Inc. (IEEE) |
| Publisher Date | 1997-08-26 |
| Access Restriction | Subscribed |
| Rights Holder | Institute of Electrical and Electronics Engineers, Inc. (IEEE) |
| Subject Keyword | Thermoelectricity Tin Thermal conductivity Doping Phonons Scattering Sparks Plasma properties Lattices Grain boundaries |
| Content Type | Text |
| Resource Type | Article |
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