NDLI: High figure of merit in Ce-filled skutterudites

Content Provider	IEEE Xplore Digital Library
Author	Fleurial, J.-P. Borshchevsky, A. Caillat, T. Morelli, D.T. Meisner, G.P.
Copyright Year	1996
Description	Author affiliation: Jet Propulsion Lab., California Inst. of Technol., Pasadena, CA, USA (Fleurial, J.-P.)
Abstract	New thermoelectric materials with superior transport properties at high temperatures have been discovered. These materials are part of the large family of skutterudites, a class of compounds which have shown a good potential for thermoelectric applications. The composition of these novel materials, called filled skutterudites, is derived from the skutterudite crystal structure and can be represented by the formula LnT/sub 4/Pn/sub 12/ (Ln=rare earth, Th; T=Fe, Rn, Os, Co, Rh, Ir; Pn=P, As, Sb). In these compounds, the empty octants of the skutterudite structure which are formed in the TPn/sub 3/ (/spl sim/T/sub 4/Pn/sub 12/) framework are filled with a rare earth element. Some of these compositions, based on CeFe/sub 4/Sb/sub 12/, have been prepared by a combination of melting and powder metallurgy techniques and have shown exceptional thermoelectric properties in the 350-700/spl deg/C temperature range. At room temperature, CeFe/sub 4/Sb/sub 12/ behaves as a p-type semimetal, but with a low thermal conductivity and surprisingly large Seebeck coefficient. These results are consistent with some recent band structure calculations on these compounds. Replacing Fe with Co in CeFe/sub 4/Sb/sub 12/ and increasing the Co:Fe atomic ratio resulted in an increase in the Seebeck coefficient values. The possibility of obtaining n-type conductivity filled skutterudites for Co:Fe values higher than 1:3 is currently being investigated. Measurements on bulk samples with a CeFe/sub 3.5/Co/sub 0.5/Sb/sub 12/ atomic composition and p-type conductivity resulted in dimensionless figure of merit ZT values of 1.4 at 600/spl deg/C.
Starting Page	91
Ending Page	95
File Size	546587
Page Count	5
File Format	PDF
ISBN	0780332210
DOI	10.1109/ICT.1996.553263
Language	English
Publisher	Institute of Electrical and Electronics Engineers, Inc. (IEEE)
Publisher Date	1996-03-26
Publisher Place	USA
Access Restriction	Subscribed
Rights Holder	Institute of Electrical and Electronics Engineers, Inc. (IEEE)
Subject Keyword	Thermoelectricity Crystalline materials Atomic measurements Thermal conductivity Composite materials Earth Powders Temperature distribution Iron Conductivity measurement
Content Type	Text
Resource Type	Article

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